Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 5.414 IF 5.414
  • IF 5-year value: 5.958 IF 5-year
  • CiteScore value: 9.7 CiteScore
  • SNIP value: 1.517 SNIP 1.517
  • IPP value: 5.61 IPP 5.61
  • SJR value: 2.601 SJR 2.601
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 191 Scimago H
    index 191
  • h5-index value: 89 h5-index 89
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Submitted as: measurement report 27 Apr 2020

Submitted as: measurement report | 27 Apr 2020

Review status
This preprint is currently under review for the journal ACP.

Measurement Report: Aircraft Observations of Ozone, Nitrogen Oxides, and Volatile Organic Compounds over Hebei Province, China

Sarah E. Benish1, Hao He1, Xinrong Ren1,2, Sandra J. Roberts3, Ross J. Salawitch1,3, Zhangqing Li1,4, Fei Wang4,5, Yuying Wang6, Fang Zhang4, Min Shao7, Sihua Lu7, and Russell R. Dickerson1 Sarah E. Benish et al.
  • 1Departmentof Atmospheric and Oceanic Science, University of Maryland, College Park, MD 20742, USA
  • 2Air Resources Laboratory, National Oceanic and Atmospheric Administration, College Park, MD 20740, USA
  • 3Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
  • 4State Key Laboratory of Earth Surface Processes and Resource Ecology, College of Global Change and Earth System Science, Beijing Normal University, Beijing, 100875, China
  • 5Key Laboratory for Cloud Physics, Chinese Academy of Meteorological Sciences, Beijing, 100081, China
  • 6Key Laboratory for Aerosol–Cloud–Precipitation of China Meteorological Administration, School of Atmospheric Physics, Nanjing University of Information Science and Technology, Nanjing, 21004, China
  • 7College of Environmental Science and Engineering, Peking University, Beijing, 100871, China

Abstract. To provide insight into the planetary boundary layer (PBL) production of ozone (O3) over the North China Plain, the Air chemistry Research in Asia (ARIAs) campaign conducted aircraft measurements of air pollutants over Hebei Province, China between May and June 2016. We evaluate vertical profiles of trace gas species including O3, nitrogen oxides (NOx), carbon monoxide (CO), and volatile organic compounds (VOCs) and relate to rates of O3 production. This analysis shows measured O3 levels ranged from 52 to 142 ppbv, with the peak median concentration (~ 94 ppbv) occurring between 1000 and 1500 m. The NOx concentrations exhibited strong spatial and altitudinal variations, ranging from 0.15 to 49 ppbv. Ratios of CO / NOy and CO / CO2 indicate the prevalence of low efficiency combustion from biomass burning and residential coal burning. Concentrations of total measured VOCs from 26 whole air canisters reveals alkanes dominate the total measured volume mixing ratio of VOCs (68 %) and we see evidence of vehicular emissions, fuel and solvent evaporation, and biomass burning sources. Alkanes and alkenes/alkynes are responsible for 74 % of the total VOC reactivity assessed by calculating the OH loss rates, while aromatics contribute the most to the total Ozone Formation Potential (OFP) (43 %) with toluene, m/p-xylene, ethylene, propylene, and i-pentane playing significant roles in the aloft production of O3 in this region. In the PBL below 500 m, box model calculations constrained by measured precursors indicate the peak rate of mean O3 production was ~ 7 ppbv/hour. Pollution frequently extended above the PBL into the lower free troposphere around 3000 m, where NO2 mixing ratios (~ 400 pptv) led to net production rates of O3 up to ~ 3 ppbv/hour; this pollution can travel substantial distances downwind. The O3 sensitivity regime is determined to be NOx-limited throughout the PBL, while more VOC-limited at low altitudes near urban centres, demonstrating both VOCs and NOx need further control to reduce aloft O3 over Hebei.

Sarah E. Benish et al.

Interactive discussion

Status: open (extended)
Status: open (extended)
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
[Subscribe to comment alert] Printer-friendly Version - Printer-friendly version Supplement - Supplement

Sarah E. Benish et al.

Sarah E. Benish et al.


Total article views: 426 (including HTML, PDF, and XML)
HTML PDF XML Total BibTeX EndNote
302 121 3 426 3 7
  • HTML: 302
  • PDF: 121
  • XML: 3
  • Total: 426
  • BibTeX: 3
  • EndNote: 7
Views and downloads (calculated since 27 Apr 2020)
Cumulative views and downloads (calculated since 27 Apr 2020)

Viewed (geographical distribution)

Total article views: 335 (including HTML, PDF, and XML) Thereof 334 with geography defined and 1 with unknown origin.
Country # Views %
  • 1



No saved metrics found.


No discussed metrics found.
Latest update: 05 Jul 2020
Publications Copernicus
Short summary
Airborne observations of ozone and related pollutants show smog was pervasive in Spring 2016 over Hebei Province, China. We find high amounts of ozone precursors throughout and even above the PBL, continuing to generate ozone at high rates to be potentially transported downwind. Concentrations even in the rural areas of this highly industrialized province promote wide spread ozone production and we show that to improve air quality over Hebei, both NOx and VOCs should be targeted.
Airborne observations of ozone and related pollutants show smog was pervasive in Spring 2016...