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© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 26 Oct 2018

Research article | 26 Oct 2018

Review status
This discussion paper is a preprint. It is a manuscript under review for the journal Atmospheric Chemistry and Physics (ACP).

Simulation of SOA Formation from the Photooxidation of Monoalkylbenzenes in the Presence of Aqueous Aerosols Containing Electrolytes under Various NOx Levels

Chufan Zhou, Myoseon Jang, and Zechen Yu Chufan Zhou et al.
  • Department of Environmental Engineering Sciences, University of Florida, Gainesville, 32611, USA

Abstract. The formation of secondary organic aerosols (SOAs) from the photooxidation of three monoalkylbenzenes (toluene, ethylbenzene, and n-propylbenzene) in the presence of inorganic seeds (SO42−-NH4+-H2O system) under varying NOx levels has been simulated using the Unified Partitioning-Aerosol Phase Reaction (UNIPAR) model. The evolution of the volatility-reactivity distribution (mass-base stoichiometric coefficient, αi) of oxygenated products, which were created by the near-explicit gas kinetic mechanism, was integrated with the model using the parameters linked to the concentrations of HO2 and RO2 radicals. This dynamic distribution was applied to estimate the model parameters related to the thermodynamic constants of the products in multiple phases (e.g., the gas phase, organic phase, and inorganic phase) and the reaction rate constants in the aerosol phase. The SOA mass was predicted through the partitioning and aerosol chemistry processes of the oxygenated products in both the organic phase and aqueous solution containing electrolytes, with the assumption of organic-inorganic phase separation. The prediction of the time series SOA mass (12-hr), against the aerosol data obtained from an outdoor photochemical smog chamber, was improved by the dynamic αi set compared to the prediction using the fixed αi set. Overall, the effect of an aqueous phase containing electrolytes on SOA yields was more important than that of the NOx level under our simulated conditions or the utilization of the age-driven αi set. Regardless of the NOx conditions, the SOA yields for the three aromatics were significantly higher in the presence of wet electrolytic seeds than those obtained with dry seeds or no seed. When increasing the NOx level, the fraction of organic matter (OM) produced by aqueous reactions to the total OM increased due to the increased formation of relatively volatile organic nitrates and peroxyacyl nitrate like products. The predicted partitioning mass fraction increased as the alkyl chain length increases but the organic mass produced via aerosol phase reactions decreased due to the increased activity coefficient of the organic compounds containing longer alkyl chains. Overall, the lower mass-base SOA yield was seen in the longer alkyl-substituted benzene in both the presence and absence of inorganic seeded aerosols. However, the difference of mole-base SOA yields of three monoalkylbenzenes becomes small because the highly reactive organic species (i.e., glyoxal) mainly originates from ring opening products without alkyl side chain. UNIPAR predicted the conversion of hydrophilic, acidic sulfur species to non-electrolytic dialkyl-organosulfate (diOS) in the aerosol. Thus, the model predicted the impact of diOS on both hygroscopicity and acidity, which subsequently influenced aerosol growth via aqueous reactions.

Chufan Zhou et al.
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Chufan Zhou et al.
Chufan Zhou et al.
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Short summary
The formation of secondary organic aerosol (SOA) from the photooxidation of three monoalkylbenzenes (toluene, ethylbenzene, and n-propylbenzene) has been simulated using the SOA model under varying environments (temperature, humidity, sunlight, NOx levels, electrolytic inorganic seed (acidity and water content), and aging). The model demonstrates that the effect of an electrolytic aqueous phase on SOA formation is more critical than that of NOx levels under SO2-rich polluted urban environments.
The formation of secondary organic aerosol (SOA) from the photooxidation of three...