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© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 17 Dec 2018

Research article | 17 Dec 2018

Review status
This discussion paper is a preprint. It is a manuscript under review for the journal Atmospheric Chemistry and Physics (ACP).

Emission of volatile halogenated organic compounds over various landforms at the Dead Sea

Moshe Shechner1, Alex Guenther2, Robert Rhew3, Asher Wishkerman4,5, Qian Li1, Donald Blake2, Gil Lerner1, and Eran Tas1 Moshe Shechner et al.
  • 1The Robert H. Smith Faculty of Agricultural, Food & Environment, Department of Soil and Water Sciences, The Hebrew University of Jerusalem, Rehovot, Israel
  • 2Department of Earth System Science, University of California, Irvine, CA, USA; Department of Geography at Berkeley
  • 3Department of Geography and Berkeley Atmospheric Sciences Center, University of California, Berkeley, Berkeley, California 94720, United States
  • 4Ruppin Academic Center, Michmoret, Israel
  • 5Department of Chemistry, University of California, Irvine, Irvine, CA 92697

Abstract. Volatile halogenated organic compounds (VHOCs), such as methyl halides (CH3X; X = Br, Cl and I) and very short-lived halogenated substances (VSLS; CHBr3, CH2Br2, CHBrCl2, C2HCl3, CHCl3 and CHBr2Cl) are well known for their significant influence on ozone concentrations and oxidation capacity of the troposphere and stratosphere, and for their key role in aerosol formation. Insufficient characterization of the sources and emission rate of VHOCs limits our present ability to understand and assess their impact in both the troposphere and the stratosphere. Over the last two decades several natural terrestrial sources for VHOCs, including soil and vegetation, have been identified, but our knowledge about emission rates from these sources and their responses to changes in ambient conditions remains limited. Here we report measurements of the mixing ratios and the fluxes of several chlorinated and brominated VHOCs from different landforms and vegetated sites at the Dead Sea during different seasons. Fluxes were highly variable but were generally positive (emissive), corresponding with elevated mixing ratios for all of the VHOCs investigated in the four investigated site types – bare soil, coastal, cultivated and natural vegetated sites – except for fluxes of CH3I and C2HCl3 over the vegetated sites. In contrast to previous reports, we also observed emissions of brominated trihalomethanes, with net molar fluxes ordered as follows: CHBr2Cl > CHBr3 > CHBrCl2 > CHCl3. This finding can be explained by the enrichment of soil with Br. Correlation analysis, in agreement with recent studies, indicated common controls for the formation and emission of all the above trihalomethanes but also for CH2Br2. Also in line with previous reports, we observed elevated emissions of CHCl3 and C2HCl3 from mixtures of soil and different salt-deposited structures; the high correlations of flux with methyl halides, and particularly with CH3I, suggested that at least CH3I is also emitted via similar mechanisms or is subjected to similar controls. Overall, our results indicate elevate emission of VHOCs from bare soil under semi-arid conditions. Along with other recent studies, our findings point to the strong emission potential of a suite of VHOCs from saline soils and salt lakes, and call for additional studies of emission rates and mechanisms of VHOCs from saline soils and salt lakes.

Moshe Shechner et al.
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Status: final response (author comments only)
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Moshe Shechner et al.
Moshe Shechner et al.
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Short summary
Along with other recent studies, our findings point to strong emission of a suite of volatile halogenated organic compounds (VHOCs) from saline soils and salt lakes. Some of the emitted VHOCs were not known to be emitted from terrestrial sources and our observations point to apparent new common controls for the emission of several VHOCs. These findings are important milestone toward a more complete understanding of the effect of VHOCs on atmospheric ozone concentrations and oxidation capacity.
Along with other recent studies, our findings point to strong emission of a suite of volatile...