Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 9 2 2009 10.5194/acpd-9-8757-2009 http://www.atmos-chem-phys-discuss.net/9/8757/2009/ http://www.atmos-chem-phys-discuss.net/9/8757/2009/acpd-9-8757-2009.html http://www.atmos-chem-phys-discuss.net/9/8757/2009/acpd-9-8757-2009.pdf 8757 8789 2009-04-01 IASI measurements of reactive trace species in biomass burning plumes P.-F. Coheur pfcoheur@ulb.ac.be L. Clarisse S. Turquety D. Hurtmans C. Clerbaux Spectroscopie de l'Atmosphère, Service de Chimie Quantique et de Photophysique, Université Libre de Bruxelles (U.L.B.), Brussels, Belgium UPMC Université Paris 06, CNRS UMR8190, LATMOS/IPSL, France now at: UPMC Université Paris 06, Laboratoire de Météorologie Dynamique/IPSL, Ecole Polytechnique, Palaiseau, France Research Associate and Scientific Research Worker with the FRS-F.N.R.S, Belgium This work presents observations of a series of short-lived species in biomass burning plumes from the Infrared Atmospheric Sounding Interferometer (IASI), launched onboard the MetOp-A platform in October 2006. The strong fires that have occurred in the Mediterranean Basin – and particularly Greece – in August 2007, and those in Southern Siberia and Eastern Mongolia in the early spring of 2008 are selected to support the analyses. We show that the IASI infrared spectra in these fire plumes contain distinctive signatures of ammonia (NH₃), ethene (C₂H₄), methanol (CH₃OH) and formic acid (HCOOH) in the atmospheric window between 800 and 1200 cm^−1, with some noticeable differences between the plumes. Peroxyacetyl nitrate (CH₃COO₂NO₂, abbreviated as PAN) was also observed in some plumes and a tentative assignment of a broadband absorption spectral feature to acetic acid (CH₃COOH) is made. For several of these species these are the first reported measurements made from space in nadir geometry. The IASI measurements are analyzed for plume height and concentration distributions of NH₃, C₂H₄ and CH₃OH. The Greek fires are studied in greater detail for the days associated with the largest emissions. In addition to providing information on the spatial extent of the plume, the IASI retrievals allow an estimate of the total mass emissions for NH₃, C₂H₄ and CH₃OH. 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