Atmos. Chem. Phys. Discuss., 9, 8757-8789, 2009
www.atmos-chem-phys-discuss.net/9/8757/2009/
doi:10.5194/acpd-9-8757-2009
© Author(s) 2009. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
IASI measurements of reactive trace species in biomass burning plumes
P.-F. Coheur1,**, L. Clarisse1,**, S. Turquety2,*, D. Hurtmans1, and C. Clerbaux1,2
1Spectroscopie de l'Atmosphère, Service de Chimie Quantique et de Photophysique, Université Libre de Bruxelles (U.L.B.), Brussels, Belgium
2UPMC Université Paris 06, CNRS UMR8190, LATMOS/IPSL, France
*now at: UPMC Université Paris 06, Laboratoire de Météorologie Dynamique/IPSL, Ecole Polytechnique, Palaiseau, France
**Research Associate and Scientific Research Worker with the FRS-F.N.R.S, Belgium

Abstract. This work presents observations of a series of short-lived species in biomass burning plumes from the Infrared Atmospheric Sounding Interferometer (IASI), launched onboard the MetOp-A platform in October 2006. The strong fires that have occurred in the Mediterranean Basin – and particularly Greece – in August 2007, and those in Southern Siberia and Eastern Mongolia in the early spring of 2008 are selected to support the analyses. We show that the IASI infrared spectra in these fire plumes contain distinctive signatures of ammonia (NH3), ethene (C2H4), methanol (CH3OH) and formic acid (HCOOH) in the atmospheric window between 800 and 1200 cm−1, with some noticeable differences between the plumes. Peroxyacetyl nitrate (CH3COO2NO2, abbreviated as PAN) was also observed in some plumes and a tentative assignment of a broadband absorption spectral feature to acetic acid (CH3COOH) is made. For several of these species these are the first reported measurements made from space in nadir geometry. The IASI measurements are analyzed for plume height and concentration distributions of NH3, C2H4 and CH3OH. The Greek fires are studied in greater detail for the days associated with the largest emissions. In addition to providing information on the spatial extent of the plume, the IASI retrievals allow an estimate of the total mass emissions for NH3, C2H4 and CH3OH. Enhancement ratios are calculated for the latter relative to carbon monoxide (CO), giving insight in the chemical processes occurring during the transport, the first day after the emission.

Citation: Coheur, P.-F., Clarisse, L., Turquety, S., Hurtmans, D., and Clerbaux, C.: IASI measurements of reactive trace species in biomass burning plumes, Atmos. Chem. Phys. Discuss., 9, 8757-8789, doi:10.5194/acpd-9-8757-2009, 2009.
 
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