Atmospheric Chemistry and Physics Discussions
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10.5194/acpd-9-8071-2009
http://www.atmos-chem-phys-discuss.net/9/8071/2009/
http://www.atmos-chem-phys-discuss.net/9/8071/2009/acpd-9-8071-2009.html
http://www.atmos-chem-phys-discuss.net/9/8071/2009/acpd-9-8071-2009.pdf
8071
8099
2009-03-26
n-Aldehydes (C<sub>6</sub>–C<sub>10</sub>) in snow samples collected at the high alpine research station Jungfraujoch during CLACE 5
K. Sieg
E. Starokozhev
E. Fries
S. Sala
W. Püttmann
Institute of Atmospheric and Environmental Science, Dept. of Analytical Environmental Chemistry, J. W. Goethe-University Frankfurt/Main, Germany
Institute of Environmental Systems Research, University of Osnabrück, Germany
Institute of Atmospheric and Environmental Science, Dept. of Experimental Atmospheric Research, J. W. Goethe-University Frankfurt/Main, Germany
Samples of freshly fallen snow were collected at the high alpine research
station Jungfraujoch, Switzerland, during the Cloud and Aerosol
Characterization Experiments (CLACE) 5 in February and March 2006. Sampling
was carried out on the Sphinx platform. Headspace-solid-phase-dynamic
extraction (HS-SPDE) combined with gas chromatography/mass spectrometry
(GC/MS) was used to quantify C<sub>6</sub>–C<sub>10</sub> n-aldehydes in the snow
samples. The most abundant n-aldehyde was n-hexanal (median concentration
1.324 μg L<sup>−1</sup>) followed by n-nonanal, n-decanal, n-octanal and
n-heptanal (median concentrations 1.239, 0.863, 0.460, and 0.304 μg L<sup>−1</sup>,
respectively). A wide range of concentrations was found among
individual snow samples, even for samples taken at the same time. Higher
median concentrations of all n-aldehydes were observed when air masses
reached Jungfraujoch from the north-northwest in comparison to air masses
arriving from the southeast-southwest. Results suggest that the n-aldehydes
detected most likely are of direct and indirect biogenic origin, and that
they entered the snow through the particle phase.
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