1Université de Toulouse, UPS, LA (Laboratoire d'Aérologie), 14 avenue Edouard Belin, 31400 Toulouse, France
2CNRS, LA (Laboratoire d'Aérologie), 31400 Toulouse, France
3School of Environmental Sciences, University of East Anglia, Norwich, UK
4Department of Chemistry, University of Toronto, Toronto, Canada
5Facility for Airborne Atmospheric Measurement, National Centre for Atmospheric Science, Cranfield, UK
*now at: Facility for Ground Atmospheric Measurements, National Centre for Atmospheric Science, University of York, Heslington, York, UK
Abstract. A bi-dimensional latitudinal-vertical meterological model coupled with O3-NOx-VOC chemistry is used to reproduce the distribution of ozone and precursors in the boundary layer over West Africa during the African Monsoon Multidisciplinary Analysis (AMMA) campaign as observed on board the Facility for Airborne Atmospheric Measurements (FAAM) BAe 146 Atmospheric Research Aircraft. The model reproduces the increase of ozone mixing ratios in the boundary layer observed between the forested region south of 13° N and the Sahelian area northward. Sensitivity and budget analysis reveals that the intertropical convergence zone is a moderate source of O3 rich-air in the boundary layer due to convective downdrafts. Dry deposition drives the ozone minimum over the vegetated area. The combination of high NOx emissions from soil north of 13° N and northward advection by the monsoon flux of VOC-enriched air masses contributes to the ozone maximum simulated at higher latitudes. Simulated OH exhibit a well marked latitudinal gradient with minimum concentrations over the vegetated region where the reactions with biogenic compounds predominate. The model underestimates the observed OH mixing ratios, however this model discrepancy has slight effect on ozone budget and does not alter the conclusions.