Atmos. Chem. Phys. Discuss., 9, 26673-26695, 2009
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Overview of mercury measurements in the Antarctic troposphere
A. Dommergue1, F. Sprovieri2, N. Pirrone2, R. Ebinghaus3, S. Brooks4, J. Courteaud1, and C. Ferrari1
1Laboratoire de Glaciologie et Géophysique de l'Environnement, CNRS – Université Joseph Fourier Grenoble, 54 Rue Molière, 38400 St Martin d'Hères, France
2CNR – Institute on Atmospheric Pollution Research, Division of Rende, Italy
3GKSS Research Centre Geesthacht, Institute for Coastal Research, Max-Planck-Str. 1, 21502 Geesthacht, Germany
4NOAA Air Resources Laboratory, Atmospheric Turbulence and Diffusion Division, USA

Abstract. Polar ecosystems are considered to be the last pristine environments of the Earth relatively uninfluenced by human activities. Antarctica in particular, compared to the Arctic is considered to be even less affected by any kind of anthropogenic influences. Once contaminants reach the polar regions, their lifetime in the troposphere depends on local removal processes. Atmospheric mercury, in particular, has unique characteristics that include long-range transport to polar regions and the transformation to more toxic and water-soluble compounds that may potentially become bioavailable. These chemical-physical properties have given mercury on the priority list of an increasing number of international, European and national conventions and agreements aimed at the protection of the ecosystems including human health (i.e., GEO, UNEP, AMAP, UN-ECE, HELCOM, OSPAR) thus stimulating a significant amount of research including measurements of Hg0 reaction rate constant with atmospheric oxidants, experimental and modelling studies in order to understand the cycling of Hg in polar regions and its impact to these ecosystems. Special attention in terms of contamination of polar regions, is paid to the consequences of the springtime phenomena, referred to as ''atmospheric mercury depletion event'' (AMDE), during which elemental gaseous mercury (GEM or Hg0) through a series of photochemically-initiated reactions involving halogens, may be converted to a reactive form that may accumulate in polar ecosystems. The discovery of the AMDE, first noted in the Arctic, has also been observed at both poles and was initially considered to result in an important net input of atmospheric Hg into the polar surfaces. However, recent studies point out that complex processes take place after deposition that may result in less significant net-inputs from the atmosphere since a fraction, sometimes significant of deposited Hg may be recycled. Therefore, the contribution of this unique reactivity occurring in polar atmospheres to the global budget of atmospheric Hg and the role played by snow and ice surfaces of these regions are important issues. This paper presents a review of atmospheric mercury studies conducted in the Antarctic troposphere, both at coastal locations and on the Antarctic Plateau since 1985. Our current understanding of atmospheric reactivity in this region is also presented.

Citation: Dommergue, A., Sprovieri, F., Pirrone, N., Ebinghaus, R., Brooks, S., Courteaud, J., and Ferrari, C.: Overview of mercury measurements in the Antarctic troposphere, Atmos. Chem. Phys. Discuss., 9, 26673-26695, doi:10.5194/acpd-9-26673-2009, 2009.
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