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	<journal>
		<journal_title>Atmospheric Chemistry and Physics Discussions</journal_title>
		<journal_url>www.atmos-chem-phys-discuss.net</journal_url>
		<issn>1680-7367</issn>
		<eissn>1680-7375</eissn>
		<volume_number>9</volume_number>
		<issue_number>6</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/acpd-9-23465-2009</doi>
	<article_url>http://www.atmos-chem-phys-discuss.net/9/23465/2009/</article_url>
	<abstract_html>http://www.atmos-chem-phys-discuss.net/9/23465/2009/acpd-9-23465-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys-discuss.net/9/23465/2009/acpd-9-23465-2009.pdf</fulltext_pdf>
	<start_page>23465</start_page>
	<end_page>23504</end_page>
	<publication_date>2009-11-03</publication_date>
	<article_title content_type="html">Atmospheric total gaseous mercury (TGM) concentrations and wet and dry deposition of mercury at a high-altitude mountain peak in south China</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>X. W. Fu</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>X. Feng</name>
			<email>fengxinbin@vip.skleg.cn</email>
		</author>
		<author numeration="3" affiliations="2">
			<name>Z. Q. Dong</name>
		</author>
		<author numeration="4" affiliations="1,3">
			<name>R. S. Yin</name>
		</author>
		<author numeration="5" affiliations="1,3">
			<name>J. X. Wang</name>
		</author>
		<author numeration="6" affiliations="2">
			<name>Z. R. Yang</name>
		</author>
		<author numeration="7" affiliations="1,3">
			<name>H. Zhang</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China</affiliation>
		<affiliation numeration="2" content_type="html">Guizhou Environmental Science Research Institute, Guiyang 550002, China</affiliation>
		<affiliation numeration="3" content_type="html">Graduate University of the Chinese Academy of Sciences, Beijing 100049, China</affiliation>
	</affiliations>
	<abstract content_type="html">China is regarded as the largest contributor of mercury (Hg) to the global atmospheric Hg
budget. However, concentration levels and depositions of atmospheric Hg in China are poorly
known. Continuous measurements of atmospheric total gaseous mercury (TGM) were carried out
from May 2008 to May 2009 at the summit of Mt. Leigong in south China. Wet and dry
deposition fluxes of Hg were also calculated following collection of precipitation,
throughfall and litterfall. Atmospheric TGM concentrations averaged 2.80&amp;plusmn;1.51 ng m&lt;sup&gt;&amp;minus;3&lt;/sup&gt;, which was highly elevated compared to global background values but
much lower than semi-rural and industrial/urban areas in China, indicating great emissions
of Hg in central, south and southwest China. Seasonal and diurnal variations of TGM were
observed, which reflected variations in source intensity, deposition processes and
meteorological factors. Wet deposition of Hg was quite low, while its dry deposition of Hg
(litterfall + throughfall-direct wet deposition) constituted a major portion of total
deposition (~88% for total mercury (THg) and 84% for methyl mercury (MeHg)). This
highlights the importance of vegetation to Hg atmospheric cycling. In a remote forest
ecosystem of China, dry deposition of TGM, especially gaseous elemental mercury (GEM), was
very important for the depletion of atmospheric Hg. Elevated TGM level in ambient air may
accelerate the foliar uptake of Hg through air which may partly explain the elevated Hg dry
deposition fluxes observed in Mt. Leigong.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Aspmo,~K., Temme,~C., Berg,~T., Ferrari,~C., Gauchard,~P A., Fain,~X., and Wibetoe,~G.: Mercury in the atmosphere, snow and melt water ponds in the North Atlantic Ocean during Arctic summer, Environ. Sci. Technol., 40, 4083â€“4089, 2006. </reference>
		<reference numeration="2" content_type="text"> Brosset,~C. and Lord,~E.: Methylmercury in ambient air, Method of determination and some measurement results, Water Air Soil Pollut., 82, 739â€“750, 1995. </reference>
		<reference numeration="3" content_type="text"> Bushey,~J T., Mallana,~A G., Montesdeoca,~M R., and Driscoll,~C T.: Mercury dynamics of a~northern hardwood canopy, Atmos. Environ., 42, 6905â€“6914, 2008. </reference>
		<reference numeration="4" content_type="text"> Choi,~H D., Sharac,~T J., and Holsen,~T M.: Mercury deposition in the Adirondacks: A~comparison between precipitation and throughfall, Atmos. Environ., 42, 1818â€“1827, 2008. </reference>
		<reference numeration="5" content_type="text"> Erichsen,~J A., Gustin,~M S., Schorran,~D E., Johnson,~D W., Lindberg, ~S E., and Coleman,~J S.: Accumulation of atmospheric mercury in forest foliage, Atmos. Environ., 37, 1613â€“1622, 2003. </reference>
		<reference numeration="6" content_type="text"> Feng,~X., Shang,~L., Wang,~S., Tang,~S., and Zheng,~W.: Temporal variation of total gaseous mercury in the air of Guiyang, China,~J. Geophys. Res., 109, D03303, doi:10.1029/2003JD004159, 2004. </reference>
		<reference numeration="7" content_type="text"> Feng,~X., Wang,~S., Qiu,~G., Hou,~Y., and Tang,~S.: Total gaseous mercury emissions from soil in Guiyang, Guyizhou, China,~J. Geophys. Res., 110, D14306, doi:10.1029/2004JD005643, 2005. </reference>
		<reference numeration="8" content_type="text"> Feng,~X. and Qiu,~G.: Mercury pollution in Guizhou, China â€“ an overview, Sci. Total Environ., 400, 227-­237, 2008. </reference>
		<reference numeration="9" content_type="text"> Fitzgerald,~W F.: Is mercury increasing in the atmosphere? The need for an atmospheric mercury network (AMNET), Water Air Soil Pollut., 80, 245â€“254, 1995. </reference>
		<reference numeration="10" content_type="text"> Friedli,~H R., Radke,~L F., Prescott,~R., Li,~P., Woo,~J H., and Carmichael,~G R.: Mercury in atmosphere around Japan, Korea and China as observed during the 2001 ACE-Asia field campaign: Measurements, distributions, sources, and implication,~J. Geophys. Res., 109, D19S25, doi:10.1029/2003JD004244, 2004. </reference>
		<reference numeration="11" content_type="text"> Fu,~X W., Feng,~X B., Zhu,~W Z., Wang,~S F., and Lu,~J.: Total gaseous mercury concentrations in ambient air in the eastern slope of Mt. Gongga, South-Eastern fringe of the Tibetan plateau, China, Atmos. Environ., 42, 70â€“979, 2008a. </reference>
		<reference numeration="12" content_type="text"> Fu,~X W., Feng,~X B., and Wang,~S F.: Exchange fluxes of Hg between surfaces and atmosphere in the eartern flank of Mount Gongga, Sichuan province, southwestern China,~J. Geophys. Res., 113, D20306, doi:10.1029/2008JD009814, 2008b. </reference>
		<reference numeration="13" content_type="text"> Fu,~X W., Feng,~X B., Zhu,~W Z., Rothenberg,~S., Yao,~H., Liu,~N., and Yin,~R S.: Elevated atmospheric deposition and dynamics of mercury in a~remote upland forest of Southwestern China, Environ. Pollut., in review, 2009a. </reference>
		<reference numeration="14" content_type="text"> Fu,~X W., Feng,~X B., Wang,~S F., Rothenberg,~S., Shang,~L H., Li,~Z. ~G., and Qiu,~G L.: Temporal and spatial distributions of total gaseous mercury concentrations in ambient air in a~mountainous area in southwestern China: Implications for industrial and domestic mercury emissions in remote areas in China, Sci. Total Environ., 407, 306â€“2314, 2009b. </reference>
		<reference numeration="15" content_type="text"> Gabriel,~M C., Williamson,~D G., Brooks,~S., and Lindberg,~S.: Atmospheric speciation of mercury in two contrasting Southeastern US airsheds, Atmos. Environ., 39, 4947â€“4958, 2005. </reference>
		<reference numeration="16" content_type="text"> Grigal,~J A., Kolka,~R K., Fleck,~J A., and Nater,~E A.: Mercury budget of an upland-peatland watershed, Biogeochemistry, 50, 95â€“109, 2000. </reference>
		<reference numeration="17" content_type="text"> Graydon,~J A., St. Louis,~V L., Lindberg,~S E., Hintelmann,~H., and Krabbenhoft,~D P.: Investigation of mercury exchange between forest canopy vegetation and the atmosphere using a~new dynamic chamber, Environ. Sci. Technol., 40, 4680â€“4688, 2006. </reference>
		<reference numeration="18" content_type="text"> Graydon,~J A., St. Louis,~V L., Hintelmann,~H., Lindberg,~S E., Sandilands,~K A., Rudd,~J W M., Kelly,~G A., Hall,~B D., and Mowat,~L. ~D.: Long-term wet and dry deposition of total and methyl mercury in the remote boreal ecoregion of Canada, Environ. Sci. Technol., 42, 8345â€“8351, 2009. </reference>
		<reference numeration="19" content_type="text"> Greger,~M., Wang,~Y., and Neuschulz,~C.: Absence of Hg transpiration by shoot after Hg uptake by roots of six terrestrial plant species, Environ. Pollut., 134(2), 201â€“208, 2005. </reference>
		<reference numeration="20" content_type="text"> Guo,~Y N., Feng,~X B., Li,~Z G., He,~T R., Yan,~H Y., Meng,~B., Zhang ~J F., and Qiu,~G L.: Distribution and wet deposition fluxes of total and methyl mercury in Wujiang reservoir Basin, Guizhou, China, Atmos. Environ. 42, 7096â€“7103, 2008. </reference>
		<reference numeration="21" content_type="text"> Hall,~B D. and St. Louis,~V L.: Methylmercury and total mercury in plant litter decomposing in upland forests and flooded landscapes, Environ. Sci. Technol., 38, 5010â€“5021, 2004. </reference>
		<reference numeration="22" content_type="text"> Hall,~B D., Manolopoulos,~H., Hurley,~J P., Schauer,~J J., St. Louis,~V. ~L., Kenski,~D., Graydon,~J., Babiarz,~C L., Cleckner,~L B., and Keeler,~G. ~J.: Methyl and total mercury in precipitation in the Great Lakes region, Atmos. Environ., 39, 7557â€“7569, 2005. </reference>
		<reference numeration="23" content_type="text"> Kim,~K H., Lindberg,~S E., and Meyers,~T P.: Micrometeorological measurements of mercury vapor fluxes over background forest soils in eastern Tennessee, Atmos. Environ., 29, 267â€“282, 1995. </reference>
		<reference numeration="24" content_type="text"> Kim,~K H. and Kim,~M Y.: The temporal distribution characteristics of total gaseous mercury at an urban monitoring site in Seoul during 1999â€“2000, Atmos. Environ., 35, 4253â€“4263, 2001. </reference>
		<reference numeration="25" content_type="text"> Kim,~K H., Ebinghaus,~R., Schroeder,~R., Blanchard,~P., Kock,~H H., Steffen,~A., Froude,~F A., Kim,~M Y., Hong,~S M., and Kim,~J H.: Atmospheric mercury concentrations from several observatory sites in the northern hemisphere,~J. Atmos. Chem., 50, 1â€“24, 2005. </reference>
		<reference numeration="26" content_type="text"> Larssen,~T., de Wit,~H A., Wiker,~M., and Halse,~K.: Mercury budget of a~small forested boreal catchment in southeast Norway, Sci. Total Environ., 404, 290â€“296, 2008. </reference>
		<reference numeration="27" content_type="text"> Lee,~D S., Dollard,~G J., and Pepler,~S.: Gas-phase mercury in the atmosphere of the United Kingdom, Atmos. Environ., 32, 855â€“864, 1998. </reference>
		<reference numeration="28" content_type="text"> Li,~P., Feng,~X B., Shang,~L H., Qiu,~G L., Meng,~B., Liang,~P., and Zhang,~H.: Mercury pollution from artisanal mercury mining in Tongren, Guizhou, China, Atmos. Environ., 23, 2055â€“2064, 2009. </reference>
		<reference numeration="29" content_type="text"> Liang,~L., Horvat,~M., and Danilchik,~P.: A~novel analytical method for determination of picogram levels of total mercury in gasoline and other petroleum based products, Sci. Total Environ., 187, 57â€“64, 1995. </reference>
		<reference numeration="30" content_type="text"> Liang,~L., Horvat,~M., Cernichiari,~E., Gelein,~B., and Balogh,~S.: Simple solvent extraction technique of elimination of matrix interferences in the determination of methylmercury in environmental and biological samples by ethylation-gas chromatography â€“ cold vapor atomic fluorescence spectrometry, Talanta, 43, 1883â€“1888, 1996. </reference>
		<reference numeration="31" content_type="text"> Liu,~S L., Nadim,~F., Perkins,~C., Carley,~R J., Hoag,~G E., Lin,~Y H., and Chen,~L T.: Atmospheric mercury monitoring survey in Beijing, China, Chemos., 48, 97â€“107, 2002. </reference>
		<reference numeration="32" content_type="text"> Lee,~Y H., Bishop,~K H., and Munthe,~J.: Do concepts about catchment cycling of methylmercury and mercury in boreal catchments stand the test of time? Six years of atmospheric inputs and runoff export at Svartberget, northern Sweden, Sci. Total Environ., 260, 11â€“20, 2000. </reference>
		<reference numeration="33" content_type="text"> Lee,~Y H., Wangberg,~I., and Munthe,~J.: Sampling and analysis of gas-phase methylmercury in ambient air, Sci. Total Environ., 304, 107â€“113, 2003. </reference>
		<reference numeration="34" content_type="text"> Mason,~R P. and Sheu,~G.-R.: Role of the ocean in the global mercury cycle, Global Biogeochem. Cy., 16, 1093, doi:10.1029/2001GB001440., 2002. </reference>
		<reference numeration="35" content_type="text"> National Research Council: Toxicological effects of MeHg, Committee Report, Board of Environmental Studies and Toxicology, National Academy press, Washing DC, 344~pp., 2000. </reference>
		<reference numeration="36" content_type="text"> Nguyen,~H T., Kim,~K H., Kim,~M Y., Hong,~S M., Youn,~Y H., Shon,~Z. ~H., and Lee,~J S.: Monitoring of atmospheric mercury at a~Global Atmospheric Watch (GAW) site on An-Myun, Island, Korea, Water Air Soil Pollut., 185, 149â€“164, 2007. </reference>
		<reference numeration="37" content_type="text"> Obrist,~D.: Atmospheric mercury pollution due to losses of terrestrial carbon polls? Biogeochemistry, 85, 119â€“123, 2007. </reference>
		<reference numeration="38" content_type="text"> Oslo and Paris Commission: JAMP guidelines for the sampling and analysis of mercury in air and precipitation, Joint assessment and monitoring programme,~1â€“20, 1998. </reference>
		<reference numeration="39" content_type="text"> Pacyna,~E G., Pacyna,~J M., Steenhuisen,~F., and Wilson,~S.: Global anthropogenic mercury emission inventory for 2000, Atmos. Environ., 40, 4048â€“4063, 2006. </reference>
		<reference numeration="40" content_type="text"> Poissant,~L., Pilote,~M., Beauvais,~C., Constant,~P., and Zhang,~H H.: A~year of continuous measurements of three atmospheric mercury species (GEM, RGM and Hgâ€“P) in southern QuÃ©bec, Canada, Atmos. Environ., 39, 1275â€“1287, 2005. </reference>
		<reference numeration="41" content_type="text"> Poissant,~L., Pilote,~M., Yumvihoze,~E., and Lean,~D.: Mercury concentrations and foliage/atmosphere fluxes in a~maple forest ecosystem in QuÃ©bec, Canada,~J. Geophys. Res., 113, D10307, doi:10.1029/2007JD009510, 2008. </reference>
		<reference numeration="42" content_type="text"> Porvari,~P. and Verta,~M.: Total and methyl mercury concentrations and fluxes from small boreal forest catchments in Finland, Environ. Pollut. 123, 181â€“191, 2003. </reference>
		<reference numeration="43" content_type="text"> Rea,~A W., Lindberg,~S E., and Keeler,~G J.: Dry deposition and foliar leaching of mercury and selected trace elements in deciduous forest throughfall, Atmos. Environ., 35, 3453â€“3462, 2001. </reference>
		<reference numeration="44" content_type="text"> Rutter, A. P., Snyder, D. C., Stone, E. A., Schauer, J. J., Gonzalez-Abraham, R., Molina, L. T., MÃ¡rquez, C., CÃ¡rdenas, B., and de Foy, B.: In situ measurements of speciated atmospheric mercury and the identification of source regions in the Mexico City Metropolitan Area, Atmos. Chem. Phys., 9, 207â€“220, 2009. </reference>
		<reference numeration="45" content_type="text"> Schroeder,~W H. and Munthe,~J.; Atmospheric mercury â€“ an overview, Atmos. Environ., 32, 809â€“822, 1998. </reference>
		<reference numeration="46" content_type="text"> Schwesig,~D. and Matzner,~F.: Pools and fluxes of mercury and methylmercury in two forested catchments in Germany, Sci. Total Environ., 260, 213â€“223, 2000. </reference>
		<reference numeration="47" content_type="text"> Selvendiran,~P., Driscoll,~C T., Montesdeoca,~M R., and Bushey,~J T.: Inputs, storage, and transport of total and methyl mercury in two temperate forest wetlands,~J. Geophys. Res., 113, G00C01, doi:10.1029/2008JG000739, 2008. </reference>
		<reference numeration="48" content_type="text"> Sheehan,~K D., Feranadez,~I J., Kahl,~J S., and Amirbahman,~A.: Litterfall mercury in two forested watersheds at Acadia National Park, Maine, USA, Water Air Soil Pollut., 170, 249â€“264, 2006. </reference>
		<reference numeration="49" content_type="text"> Shetty,~S K., Lin,~C J., Street,~D G., and Jang,~C.: Model estimate of mercury emission from natural sources in East Asia, Atmos. Environ., 42, 8674â€“8685, 2008. </reference>
		<reference numeration="50" content_type="text"> Sigler, J. M., Mao, H., and Talbot, R.: Gaseous elemental and reactive mercury in Southern New Hampshire, Atmos. Chem. Phys., 9, 1929â€“1942, 2009. </reference>
		<reference numeration="51" content_type="text"> St. Louis,~V L., Rudd,~W. M, Kelly,~C A., Hall,~B D., Rolfhus,~K R., Scott,~K J., Lindberg,~S E., and Dong,~W J.: Importance of the forest canopy to flux of methylmercury and total mercury to boreal ecosystems, Environ. Sci. Technol., 35, 3089â€“3098, 2001. </reference>
		<reference numeration="52" content_type="text"> Stamenkovic,~J. and Gustin,~M S.: Nonstomatal versus Stomatal Uptake of Atmospheric mercury, Environ. Sci. Technol. 43, 1367â€“1372, 2009. </reference>
		<reference numeration="53" content_type="text"> Street,~D G., Hao,~J M., Wu,~Y., Jiang,~J K., Chan,~M., and Tian,~H Z.: Anthropogenic mercury emission in China, Atmos. Environ., 39, 7789â€“806, 2005. </reference>
		<reference numeration="54" content_type="text"> Tekran: Model 2527A mercury vapor analyzer user manual, Toronto, Canada, 2002. </reference>
		<reference numeration="55" content_type="text"> Travnikov,~O.: Contribution of the intercontinental atmospheric transport to mercury pollution in the Northern Hemisphere, Atmos. Environ., 39, 7541â€“7548, 2005. </reference>
		<reference numeration="56" content_type="text"> US EPA: Method 1631: Revision B, Mercury in water by Oxidation, Purge and Trap, and Cold Vapor atomic Fluorescence Spectrometry, United States Environmental Protection Agency,~1â€“33, 1999. </reference>
		<reference numeration="57" content_type="text"> US EPA: Method 1630: Methyl mercury in water by distillation, aqueous ethylation, purge and trap, and CVAFS U S. Environmental Protection Agency, Office of Water, Office of Science and Technology Engineering and Analysis Division (4303), 1200 Pennsylvania Avenue NW, Washington,~DC 20460,~1â€“41, 2001. </reference>
		<reference numeration="58" content_type="text"> Valente,~R J., Shea,~C., Humes,~K L., and Tanner,~R L.: Atmospheric mercury in the Great Smoky Mountains compared to regional and global levels, Atmos. Environ., 41, 1861â€“1873, 2007. </reference>
		<reference numeration="59" content_type="text"> Wan,~Q., Feng,~X B., Julia,~L., Zheng,~W., Song,~X J., Han,~S J., and Xu, ~H.: Atmospheric mercury in Changbai Mountain area, northeastern China â€“ Part 1: The seasonal distribution pattern of total gaseous mercury and its potential sources, Environ. Res., 109, 201â€“206, 2009a. </reference>
		<reference numeration="60" content_type="text"> Wan,~Q., Feng,~X B., Julia,~L., Zheng,~W., Song,~X J., Li,~P., Han,~S J., and Xu,~H.: Atmospheric mercury in Changbai Mountain area, northeastern China â€“ Part 2: The distribution of reactive gaseous mercury and particulate mercury and mercury deposition fluxes, Environ. Res., 109, 721â€“727, 2009b. </reference>
		<reference numeration="61" content_type="text"> Wang,~Y. Q, Zhang,~X Y., and Draxler,~R R.: TrajStat: GIS-based software that uses various trajectory statistical analysis methods to identify potential sources from long-term air pollution measurement data, Environ. Model. Soft., 24, 938â€“939, 2009. </reference>
		<reference numeration="62" content_type="text"> Wang,~Z W., Zhang,~X S., Xiao,~J S., Ci,~Z J., and Yu,~P Z.: Mercury fluxes and pools in three subtropical forested catchments, southwest China, Environ. Pollut., 157, 801â€“808, 2008. </reference>
		<reference numeration="63" content_type="text"> Witt,~E L., Kolka,~R K., Nater,~E A., and Wickman,~T R.: Influence of the forest canopy on total and methyl mercury deposition in the boreal forest, Water Air Soil Pollut., 199, 3â€“11, 2009. </reference>
		<reference numeration="64" content_type="text"> Wu,~Y., Wang,~S X., Streets,~D G., Hao,~F M., Chan,~M., and Jiang,~J K.: Trends in Anthropogenic Mercury Emissions in China from 1995 to 2003, Environ. Sci. Technol., 40, 5312â€“5318, 2007. </reference>
		<reference numeration="65" content_type="text"> Zhang,~H H., Poissant,~L., Xu,~X H., and Pilote,~M : Explorative and innovative dynamic flux bag method development and testing for mercury air-vegetation gas exchange fluxes, Atmos. Environ., 39, 7481â€“7493, 2005. </reference>
	</references>
</article>

