Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 9 5 2009 10.5194/acpd-9-22693-2009 http://www.atmos-chem-phys-discuss.net/9/22693/2009/ http://www.atmos-chem-phys-discuss.net/9/22693/2009/acpd-9-22693-2009.html http://www.atmos-chem-phys-discuss.net/9/22693/2009/acpd-9-22693-2009.pdf 22693 22738 2009-10-27 Ozone profile retrievals from the Ozone Monitoring Instrument X. Liu xiong.liu-1@nasa.gov P. K. Bhartia K. Chance R. J. D. Spurr T. P. Kurosu Goddard Earth Sciences and Technology Center, University of Maryland, Baltimore County, Baltimore, Maryland, USA Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts, USA NASA Goddard Space Flight Center, Greenbelt, Maryland, USA RT Solutions Inc., Cambridge, Massachusetts, USA Ozone profiles from the surface to about 60 km are retrieved from Ozone Monitoring Instrument (OMI) ultraviolet radiances using the optimal estimation technique. OMI provides daily ozone profiles for the entire sunlit portion of the earth at a horizontal resolution of 13 km×48 km for the nadir position. The retrieved profiles have sufficient accuracy in the troposphere to see ozone perturbations caused by convection, biomass burning and anthropogenic pollution, and to track their spatiotemporal transport. However, to achieve such accuracy it has been necessary to calibrate OMI radiances carefully (using two days of Aura/Microwave Limb Sounder data taken in the tropics). The retrieved profiles contain ~6–7° of freedom for signal, with 5–7 in the stratosphere and 0–1.5 in the troposphere. Vertical resolution varies from 7–11 km in the stratosphere to 10–14 km in the troposphere. Retrieval precisions range from 1% in the middle stratosphere to 10% in the lower stratosphere and troposphere. Solution errors (i.e., root sum square of precisions and smoothing errors) vary from 1–6% in the middle stratosphere to 6–35% in the troposphere, and are dominated by smoothing errors. Total, stratospheric, and tropospheric ozone columns can be retrieved with solution errors typically in the few Dobson unit range at solar zenith angles less than 80°. Acarreta,~J R., De Haan,~J F., and Stammes,~P.: Cloud pressure retrieval using the \chemO_2-\chemO_2 absorption band at 477 \unitnm, J Geophys. Res., 109, D05204, doi:10.1029/2003JD003915, 2004. Auvray,~M. and Bey,~I.: Long-range transport to Europe: seasonal variations and implications for the European ozone budget, J Geophys. Res., 110, D11303, doi:10.1029/2004JD005503, 2005. Bhartia,~P K., McPeters,~R D., Mateer,~C L., Flynn,~L E., and Wellemeyer,~C.: Algorithm for the estimation of vertical ozone profiles from the backscattered ultraviolet technique, J Geophys. Res., 101, 18793–18806, 1996. 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