Atmos. Chem. Phys. Discuss., 9, 13299-13325, 2009
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Global carbon tetrachloride distributions obtained from the Atmospheric Chemistry Experiment (ACE)
N. D. C. Allen1, P. F. Bernath1,2, C. D. Boone2, M. P. Chipperfield3, D. Fu2,4, G. L. Manney4,5, G. C. Toon4, and D. K. Weisenstein6
1Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
2Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
3School of Earth and Environment, University of Leeds, Leeds, LS2 9JT, UK
4Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA
5Department of Physics, University of Toronto, Toronto, Ontario, Canada
6Atmospheric and Environmental Research, Inc., Lexington, Massachusetts, USA

Abstract. The first study of the global atmospheric distribution of carbon tetrachloride (CCl4), as a function of altitude and latitude, was performed using solar occultation measurements obtained by the Atmospheric Chemistry Experiment (ACE) mission using Fourier transform spectroscopy. A total of 8703 profile measurements were used in the study taken between February 2004 and August 2007. The zonal distribution of carbon tetrachloride displays a slight hemispheric asymmetry and decreasing concentration with increasing altitude at all latitudes. Maximum carbon tetrachloride concentrations are situated below 10 km in altitude with VMR (Volume Mixing Ratio) values of 100–130 ppt (parts per trillion). The highest concentrations are located about the equator and at mid-latitudes, particularly for latitudes in heavily industrialised regions (20–45° N), with values declining towards the poles. Global distributions obtained from ACE were compared with predictions from three chemistry transport models. The ACE dataset gives unique global and temporal coverage of carbon tetrachloride and its transport through the atmosphere. An estimated lifetime for carbon tetrachloride of 34±5 years was determined through correlation with CFC-11.

Citation: Allen, N. D. C., Bernath, P. F., Boone, C. D., Chipperfield, M. P., Fu, D., Manney, G. L., Toon, G. C., and Weisenstein, D. K.: Global carbon tetrachloride distributions obtained from the Atmospheric Chemistry Experiment (ACE), Atmos. Chem. Phys. Discuss., 9, 13299-13325, doi:10.5194/acpd-9-13299-2009, 2009.
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