Atmos. Chem. Phys. Discuss., 9, 13235-13269, 2009
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
The exchange of SVOCs across the air-sea interface in Singapore's coastal environment
J. He and R. Balasubramanian
Division of Environmental Science and Engineering, National University of Singapore, Engineering Drive 4, 117576, Singapore

Abstract. Coastal areas are vulnerable to the accumulation of semi-volatile organic compounds such as PAHs, OCPs and PCBs from atmospheric inputs. Dry particulate and wet depositions, and air-water diffusive exchange in the Singapore's south coastal area, where most of chemical and oil refinery industries are situated in, were estimated. Based on a yearly dataset, the mean annual dry particulate deposition fluxes of ∑16PAHs, ∑7OCPs and ∑21PCBs were 1328.8±961.1 μg m−2 y−1, 5421.4±3426.7 ng m−2 y−1 and 811.8±578.3 ng m−2 y−1, and the wet deposition of ∑16PAHs and ∑7OCPs were 6667.1±1745.2 and 115.4±98.3 μg m−2 y−1, respectively. Seasonal variation of atmospheric depositions was influenced by meteorological conditions. Air-water gas exchange fluxes had negative values for PAHs, HCHs and DDXs, indicating Singapore's south coast as a sink for the above-mentioned SVOCs. The relative contribution of each depositional process to the total atmospheric input was assessed by annual fluxes. The profile of dry particulate deposition, wet deposition and gas exchange fluxes seemed to be correlated with individual pollutant's properties such as molecular weight and Henry's law constant, etc. For the water column partitioning, the organic carbon-normalized partition coefficients between particulate and dissolved phases (KOC) for both PAHs and OCPs were obtained. The relationships between KOC of PAHs and OCPs and their respective octanol-water partition coefficient (KOW) were examined. In addition, both adsorption onto combustion-derived soot carbon and absorption into natural organic matter for PAHs in marine water column were investigated. Enrichment factors in the sea-surface microlayer (SML) of the particulate phase were 1.2~7.1 and 3.0~4.9 for PAHs and OCPs, and those of dissolved phase were 1.1~4.9 and 1.6~4.2 for PAHs and OCPs, respectively. These enrichment factors are relatively higher than those reported for nearby coastal areas, which are most likely due to more organic surfactants floating in the south coastal surface of Singapore.

Citation: He, J. and Balasubramanian, R.: The exchange of SVOCs across the air-sea interface in Singapore's coastal environment, Atmos. Chem. Phys. Discuss., 9, 13235-13269, doi:10.5194/acpd-9-13235-2009, 2009.
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