Atmos. Chem. Phys. Discuss., 9, 12675-12706, 2009
© Author(s) 2009. This work is distributed
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Impact of tropospheric nitrogen dioxide on the regional radiation budget
A. P. Vasilkov1, J. Joiner2, L. Oreopoulos2, J. F. Gleason2, P. Veefkind3, E. Bucsela4, E. A. Celarier5, R. J. D. Spurr6, and S. Platnick2
1Science Systems and Applications Inc., Lanham, MD, USA
2Goddard Space Flight Center, Greenbelt, MD, USA
3Royal Netherlands Meteorological Institute (KNMI), de Bilt, The Netherlands
4SRI International, Menlo Park, CA, USA
5University of Maryland, Baltimore County, USA
6RT Solutions, Cambridge, MA, USA

Abstract. Following the launch of several satellite ultraviolet and visible spectrometers including the Ozone Monitoring Instrument (OMI), much has been learned about the global distribution of nitrogen dioxide (NO2). NO2, which is mostly anthropogenic in origin, absorbs solar radiation at ultraviolet and visible wavelengths. We parameterized NO2 absorption for fast radiative transfer calculations. Using this parameterization with cloud, surface, and NO2 information from different sensors in the NASA A-train constellation of satellites and NO2 profiles from the Global Modeling Initiative (GMI), we compute the global distribution of net atmospheric heating due to tropospheric NO2 for January and July 2005. We assess the impact of clouds and find that because most of N02 is contained in the boundary layer in polluted regions, the cloud shielding effect can significantly reduce the net atmospheric heating due to NO2. We examine the effect of diurnal variations in NO2 emissions and chemistry on net atmospheric heating and find only a small impact of these on the daily-averaged heating. While the impact of NO2 on the global radiative forcing is small, locally it can produce instantaneous net atmospheric heating of 2–4 W/m2 in heavily polluted areas. We also examine the sensitivity of NO2 absorption to various geophysical conditions. Effects of the vertical distributions of cloud optical depth and NO2 on net atmospheric heating and downwelling radiance are simulated in detail for various scenarios including vertically-inhomogeneous convective clouds observed by CloudSat. The maximum effect of NO2 on downwelling radiance occurs when the NO2 is located in the middle part of the cloud where the optical extinction peaks.

Citation: Vasilkov, A. P., Joiner, J., Oreopoulos, L., Gleason, J. F., Veefkind, P., Bucsela, E., Celarier, E. A., Spurr, R. J. D., and Platnick, S.: Impact of tropospheric nitrogen dioxide on the regional radiation budget, Atmos. Chem. Phys. Discuss., 9, 12675-12706, doi:10.5194/acpd-9-12675-2009, 2009.
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