Atmos. Chem. Phys. Discuss., 9, 12519-12558, 2009
www.atmos-chem-phys-discuss.net/9/12519/2009/
doi:10.5194/acpd-9-12519-2009
© Author(s) 2009. This work is distributed
under the Creative Commons Attribution 3.0 License.
Review Status
This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Aerosol optical properties relevant to regional remote sensing of CCN activity and links to their organic mass fraction: airborne observations over Central Mexico and the US West Coast during MILAGRO/INTEX-B
Y. Shinozuka1,*, A. D. Clarke1, P. F. DeCarlo2,3,**, J. L. Jimenez2,4, E. J. Dunlea2, G. C. Roberts5, J. M. Tomlinson6, D. R. Collins6, S. G. Howell1, V. N. Kapustin1, C. S. McNaughton1, and J. Zhou1
1School of Ocean and Earth Science and Technology, University of Hawaii, Honolulu, HI, USA
2Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, CO, USA
3Dept. of Atmospheric and Oceanic Sciences, University of Colorado, Boulder, CO, USA
4Dept. of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
5Center for Atmospheric Sciences, Scripps Institution of Oceanography, La Jolla, CA, USA
6Department of Atmospheric Sciences, Texas A{&}M University, College Station, TX, USA
*now at: National Aeronautics and Space Administration Ames Research Center, MS 245-5, Moffett Field, CA, USA
**now at: Paul Scherrer Institut, 5232 Villigen-PSI, Switzerland

Abstract. Remote sensing of cloud condensation nuclei (CCN) would help evaluate the indirect effects of tropospheric aerosols on clouds and climate. To assess its feasibility, we examined relationships of submicron aerosol composition to CCN activity and optical properties observed during the MILAGRO/INTEX-B aircraft campaigns. An indicator of CCN activity, κ, was calculated from hygroscopicity measured under saturation. κ for dry 100-nm particles decreased with the organic fraction of non-refractory mass of submicron particles (OMF) as 10(−0.43−0.44*OMF) over Central Mexico and 10(−0.29−0.70*OMF) over the US West Coast. These fits represent the critical dry diameter, centered near 100 nm for 0.2% supersaturation but varied as κ(−1/3), within measurement uncertainty (~20%). The decreasing trends of CCN activity with the organic content, evident also in our direct CCN counts, were consistent with previous ground and laboratory observations of highly organic particles. The wider range of OMF, 0–0.8, for our research areas means that aerosol composition will be more critical for estimation of CCN concentration than at the fixed sites previously studied. Furthermore, the wavelength dependence of extinction was anti-correlated with OMF as −0.70*OMF+2.0 for Central Mexico's urban and industrial pollution air masses, for unclear reasons. The Angstrom exponent of absorption increased with OMF, more rapidly under higher single scattering albedo, as expected for the interplay between soot and colored weak absorbers (some organic species and dust). Because remote sensing products currently use the wavelength dependence of extinction albeit in the column integral form and may potentially include that of absorption, these regional spectral dependencies are expected to facilitate retrievals of aerosol bulk chemistry and CCN activity over Central Mexico.

Citation: Shinozuka, Y., Clarke, A. D., DeCarlo, P. F., Jimenez, J. L., Dunlea, E. J., Roberts, G. C., Tomlinson, J. M., Collins, D. R., Howell, S. G., Kapustin, V. N., McNaughton, C. S., and Zhou, J.: Aerosol optical properties relevant to regional remote sensing of CCN activity and links to their organic mass fraction: airborne observations over Central Mexico and the US West Coast during MILAGRO/INTEX-B, Atmos. Chem. Phys. Discuss., 9, 12519-12558, doi:10.5194/acpd-9-12519-2009, 2009.
 
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