Atmos. Chem. Phys. Discuss., 8, 9323-9346, 2008
© Author(s) 2008. This work is distributed
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
The effect of temperature and water on secondary organic aerosol formation from ozonolysis of limonene, Δ³-carene and α-pinene
Å. M. Jonsson, M. Hallquist, and E. Ljungström
Dept. of Chemistry, Atmospheric Science, University of Gothenburg, 41296 Göteborg, Sweden

Abstract. The effect of reaction temperature and how water vapour influences the formation of secondary organic aerosol (SOA) in ozonolysis of limonene, Δ3-carene and α-pinene, both regarding number and mass of particles, has been investigated by using a laminar flow reactor G-FROST. Experiments with cyclohexane and 2-butanol (~3.5×1014 molecules cm−3) as OH scavengers were compared to experiments without any scavenger. The reactions were conducted in the temperature range between 298 and 243 K, and at relative humidities between <10 and 80%. Results showed that there is still a scavenger effect on number and mass concentrations at low temperatures between experiments with and without OH scavenger. This shows that the OH chemistry is influencing the SOA formation also at these temperatures. The overall temperature dependence on SOA formation is not as strong as expected from the partitioning theory. In some cases there is even a positive temperature dependence that must be related to changes in the chemical mechanism and/or reduced rates of secondary chemistry at low temperatures. The water effect at low temperature could be explained by physical uptake and cluster stabilisation. At higher temperatures, only a physical explanation is not sufficient and the observations are in line with water changing the chemical mechanism or reaction rates. The data presented adds to the understanding of SOA contribution to atmospheric aerosol composition, new particle formation and atmospheric degradation mechanisms.

Citation: Jonsson, Å. M., Hallquist, M., and Ljungström, E.: The effect of temperature and water on secondary organic aerosol formation from ozonolysis of limonene, Δ³-carene and α-pinene, Atmos. Chem. Phys. Discuss., 8, 9323-9346, doi:10.5194/acpd-8-9323-2008, 2008.
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