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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-8-7017-2008</article-id>
<title-group>
<article-title>Why are estimates of global isoprene emissions so similar (and why is this not so for monoterpenes)?</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Arneth</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Monson</surname>
<given-names>R. K.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schurgers</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Niinemets</surname>
<given-names>Ü.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Palmer</surname>
<given-names>P. I.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Physical Geography and Ecosystems Analysis, Geobiosphere Science Centre, Lund University Sölvegatan 12, 223 62, Lund, Sweden</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Ecology and Evolutionary Biology, and Cooperative Institute for Environmental Sciences, University of Colorado, Boulder, CO, 9 80309, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institute of Agricultural and Environmental Sciences, Estonian University of Life Sciences, Kreutzwaldi 1, 51014, Tartu, Estonia</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>School of GeoSciences, University of Edinburgh, King&apos;s Buildings, Edinburgh, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>04</month>
<year>2008</year>
</pub-date>
<volume>8</volume>
<issue>2</issue>
<fpage>7017</fpage>
<lpage>7050</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/8/7017/2008/acpd-8-7017-2008.html">This article is available from http://www.atmos-chem-phys-discuss.net/8/7017/2008/acpd-8-7017-2008.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/8/7017/2008/acpd-8-7017-2008.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/8/7017/2008/acpd-8-7017-2008.pdf</self-uri>
<abstract>
<p>Emissions of biogenic volatile organic compounds (BVOC) are a chief
uncertainty in calculating the burdens of important atmospheric compounds
like tropospheric ozone or secondary organic aerosol, reflecting either
imperfect chemical oxidation mechanisms or unreliable emission estimates, or
both. To provide a starting point for a more systematic discussion we review
here global isoprene and monoterpene emission estimates to-date. We note a
surprisingly small variation in the predictions of global isoprene emission
rate that is in stark contrast with our lack of process understanding and
the small number of observations for model parameterisation and evaluation.
Most of the models are based on similar emission algorithms, using fixed
values for the emission capacity of various plant functional types. In some
studies these values are very similar, but they differ substantially in
others. The models differ also broadly with regard to their representation
of net primary productivity, method of biome coverage determination and
climate data. Their similarities with regard to the global isoprene emission
rate would suggest that the dominant parameters driving the ultimate global
estimate, and thus the dominant determinant of model sensitivity, are the
specific emission algorithm and isoprene emission capacity. Contrary to
isoprene, monoterpene estimates show significantly larger model-to-model
variation although variation in terms of leaf algorithm, emission
capacities, the way of model upscaling, vegetation cover or climatology used
in terpene models are comparable to those used for isoprene. From our
summary of published studies there appears to be no evidence that the
terrestrial modelling community has been any more successful in &quot;resolving
unknowns&quot; in the mechanisms that control global isoprene emissions, compared
to global monoterpene emissions. Rather, the proliferation of common
parameterization schemes within a large variety of model platforms lends the
illusion of convergence towards a common estimate of global isoprene
emissions. This convergence might be used to provide optimism that the
community has reached the &quot;relief phase&quot;, the phase when sufficient process
understanding and data for evaluation allows for models to converge, when
applying a recently proposed concept. We argue that there is no basis for
this apparent &quot;relief&quot; phase. Rather, we urge modellers to be bolder in
their analysis to draw attention to the fact that terrestrial emissions,
particularly in the area of biome-specific emission capacities, are unknown
rather than uncertain.</p>
</abstract>
<counts><page-count count="34"/></counts>
</article-meta>
</front>
<body/>
<back>
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