Atmos. Chem. Phys. Discuss., 8, 4561-4602, 2008
www.atmos-chem-phys-discuss.net/8/4561/2008/
doi:10.5194/acpd-8-4561-2008
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Envisat MIPAS measurements of CFC-11: retrieval, validation, and climatology
L. Hoffmann1, M. Kaufmann1, R. Spang1, R. Müller1, J. J. Remedios2, D. P. Moore2, C. M. Volk3, T. von Clarmann4, and M. Riese1
1Forschungszentrum Jülich, Institut für Chemie und Dynamik der Geosphäre (ICG-1), Jülich, Germany
2EOS, Space Research Centre, Department of Physics and Astronomy, University of Leicester, Leicester, UK
3J. W. Goethe-Universität Frankfurt, Institut für Atmosphäre und Umwelt, Frankfurt, Germany
4Forschungszentrum Karlsruhe, Institut für Meteorologie and Klimaforschung, Karlsruhe, Germany

Abstract. From July 2002 to March 2004 the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) aboard the European Space Agency's Environmental Satellite (Envisat) measured nearly continuously mid infrared limb radiance spectra. These measurements are utilised to retrieve the global distribution of the chlorofluorocarbon CFC-11 by applying a new fast forward model for Envisat MIPAS and an accompanying optimal estimation retrieval processor. A detailed analysis shows that the total retrieval errors of the individual CFC-11 volume mixing ratios are typically below 10% and that the systematic components are dominating. Contribution of a priori information to the retrieval results are less than 5 to 10%. The vertical resolution of the observations is about 3 to 4 km. The data are successfully validated by comparison with several other space experiments, an air-borne in-situ instrument, measurements from ground-based networks, and independent Envisat MIPAS analyses. The retrieval results from 425 000 Envisat MIPAS limb scans are compiled to provide a new climatological data set of CFC-11. The climatology shows significantly lower CFC-11 abundances in the lower stratosphere compared with the Reference Atmospheres for MIPAS (RAMstan V3.1) climatology. Depending on the atmospheric conditions the differences between the climatologies are up to 30 to 110 ppt (45 to 150%) at 19 to 27 km altitude. Additionally, time series of CFC-11 mean abundance and variability for five latitudinal bands are presented. The observed CFC-11 distributions can be explained by the residual mean circulation and large-scale eddy-transports in the upper troposphere and lower stratosphere. The new CFC-11 data set is well suited for further scientific studies.

Citation: Hoffmann, L., Kaufmann, M., Spang, R., Müller, R., Remedios, J. J., Moore, D. P., Volk, C. M., von Clarmann, T., and Riese, M.: Envisat MIPAS measurements of CFC-11: retrieval, validation, and climatology, Atmos. Chem. Phys. Discuss., 8, 4561-4602, doi:10.5194/acpd-8-4561-2008, 2008.
 
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