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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics Discussions</journal_title>
		<journal_url>www.atmos-chem-phys-discuss.net</journal_url>
		<issn>1680-7367</issn>
		<eissn>1680-7375</eissn>
		<volume_number>8</volume_number>
		<issue_number>6</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/acpd-8-19917-2008</doi>
	<article_url>http://www.atmos-chem-phys-discuss.net/8/19917/2008/</article_url>
	<abstract_html>http://www.atmos-chem-phys-discuss.net/8/19917/2008/acpd-8-19917-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys-discuss.net/8/19917/2008/acpd-8-19917-2008.pdf</fulltext_pdf>
	<start_page>19917</start_page>
	<end_page>19955</end_page>
	<publication_date>2008-11-28</publication_date>
	<article_title content_type="html">Estimating surface CO&lt;sub&gt;2&lt;/sub&gt; fluxes from space-borne CO&lt;sub&gt;2&lt;/sub&gt; dry air mole fraction observations using an ensemble Kalman Filter</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>L. Feng</name>
			<email>lfeng@staffmail.ed.ac.uk</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>P. I. Palmer</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>H. Bösch</name>
		</author>
		<author numeration="4" affiliations="3">
			<name>S. Dance</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">School of Geosciences, University of Edinburgh, King&apos;s Buildings, Edinburgh EH9 3JN, UK</affiliation>
		<affiliation numeration="2" content_type="html">Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH, UK</affiliation>
		<affiliation numeration="3" content_type="html">Department of Mathematics and Department of Meteorology, University of Reading, Reading RG6 6BB, UK</affiliation>
	</affiliations>
	<abstract content_type="html">We have developed an ensemble Kalman Filter (EnKF) to estimate 8-day regional
surface fluxes of CO&lt;sub&gt;2&lt;/sub&gt; from space-borne CO&lt;sub&gt;2&lt;/sub&gt; dry-air mole fraction
observations (X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt;) and evaluate the approach using a series of
synthetic experiments, in preparation for data from the NASA Orbiting
Carbon Observatory (OCO). The 32-day duty cycle of OCO alternates every 16 days
between nadir and glint measurements of backscattered solar radiation at
short-wave infrared wavelengths. The EnKF uses an ensemble of states to
represent the prior error covariance to estimate 8-day CO&lt;sub&gt;2&lt;/sub&gt; surface
fluxes over 144 geographical regions. We use a 12&amp;times;8-day lag
window, recognising that  X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt; measurements include surface flux
information from prior time windows. The observation operator that
relates surface CO&lt;sub&gt;2&lt;/sub&gt; fluxes to atmospheric distributions of  X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt;
includes: a) the GEOS-Chem transport model that relates surface fluxes
to global 3-D distributions of CO&lt;sub&gt;2&lt;/sub&gt; concentrations, which are sampled
at the time and location of OCO measurements that are cloud-free and
have aerosol optical depths &lt;0.3; and b) scene-dependent averaging
kernels that relate the CO&lt;sub&gt;2&lt;/sub&gt; profiles to X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt;, accounting for
differences between nadir and glint measurements, and the associated
scene-dependent observation errors. We show that OCO X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt;
measurements significantly reduce the uncertainties of surface CO&lt;sub&gt;2&lt;/sub&gt;
flux estimates. Glint measurements are generally better at constraining
ocean CO&lt;sub&gt;2&lt;/sub&gt; flux estimates. Nadir X&lt;sub&gt;CO&lt;sub&gt;2&lt;/sub&lt;/sub&gt; measurements over the
terrestrial tropics are sparse throughout the year because of either
clouds or smoke. Glint measurements provide the most
effective constraint for estimating tropical terrestrial CO&lt;sub&gt;2&lt;/sub&gt; fluxes
by accurately sampling fresh continental outflow over neighbouring
oceans. We also present results from sensitivity experiments that
investigate how flux estimates change with 1) bias and unbiased errors,
2) alternative duty cycles, 3) measurement density and correlations, 4)
the spatial resolution of estimated flux estimates, and 5) reducing the
length of the lag window and the size of the ensemble.</abstract>
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