Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 8 6 2008 10.5194/acpd-8-19487-2008 http://www.atmos-chem-phys-discuss.net/8/19487/2008/ http://www.atmos-chem-phys-discuss.net/8/19487/2008/acpd-8-19487-2008.html http://www.atmos-chem-phys-discuss.net/8/19487/2008/acpd-8-19487-2008.pdf 19487 19525 2008-11-17 Carbonaceous aerosols at urban influenced sites in Norway K. E. Yttri key@nilu.no C. Dye O.-A. Braathen D. Simpson E. Steinnes Norwegian Institute for Air Research, P.O. Box 100, 2027 Kjeller, Norway Norwegian Meteortological Institute, P.B. 43 Blindern, 0313 Oslo, Norway Dept. of Radio and Space Science, Chalmers University of Technology, Gothenburg, Sweden Dept. of Chemistry, Norwegian University of Science and Technology, 7491 Trondheim, Norway Little is known regarding levels and source strength of carbonaceous aerosols in Scandinavia. In the present study, ambient aerosol (PM₁₀ and PM_2.5) concentrations of elemental carbon (EC), organic carbon (OC), water-insoluble organic carbon (WINSOC), and water-soluble organic carbon (WSOC) are reported for a curbside site, an urban background site, and a suburban site in Norway in order to investigate their spatial and seasonal variations. Aerosol filter samples were collected using tandem filter sampling to correct for the positive sampling artefact introduced by semi volatile OC. Analyses were performed using the thermal optical transmission (TOT) instrument from Sunset Lab Inc., which corrects for charring during analysis. Finally, we estimated the relative contribution of OC from wood burning based on the samples content of levoglucosan. <br><br> Levels of EC varied by more than one order of magnitude between sites, likely due to the higher impact of vehicular traffic at the curbside and the urban background sites. In winter, the level of particulate organic carbon (OC_p) at the suburban site was equal to (for PM₁₀) or even higher (for PM_2.5) than the levels observed at the curbside and the urban background sites. This finding was attributed to the impact of residential wood burning at the suburban site in winter, which was confirmed by a high mean concentration of levoglucosan (407 ng m^&minus;3). This finding indicates that exposure to primary combustion derived OC_p could be equally high in residential areas as in a city center. It is demonstrated that OC_p from wood burning (OC_wood) accounted for almost all OC_p at the suburban site in winter, allowing a new estimate of the ratio TC_p/levoglucosan for both PM₁₀ and PM_2.5. Particulate carbonaceous material (PCM = Organic matter + Elemental matter) accounted for 46–83% of PM₁₀ at the sites studied when considering the positive artefact of semi volatile OC, thus being the major contributor to PM. Birch, M.E., Cary, R.A.: Elemental carbon-based method for monitoring occupational exposures to particulate diesel exhaust, Aerosol Sci. Tech., 25, 221-241, 1996. Castro, L. M., Pio, C. A., Harrison, R. M., Smith, D. J. T.: Carbonaceous aerosol in urban and rural European atmospheres: estimation of secondary organic carbon concentrations, Atmos. Environ., 33, 2771–2781, 1999. Cruz, C. N. and Pandis, S. N.: A study of the ability of pure secondary organic carbon aerosols to act as cloud condensation nuclei, Atmos. Environ., 31, 2205–2214, 1997. Dye, C. and Yttri, K. E.: Determination of monosaccharide anhydrides in atmospheric aerosols by use of high-resolution mass spectrometry combined with high performance liquid chromatography, Anal. Chem., 77, 1853–1858, 2005. EMEP: EMEP Manual for sampling and chemical analysis, Norwegian Institute for Air Research, Kjeller, EMEP/CCC-Report 1/95, 1995. Fine, P. M, Cass, G. R., and Simoneit, B. R. T.: Chemical characterization of fine particle emissions from the fireplace combustion of woods grown in the Northeastern United States, Environ. Sci. Technol., 35, 2665–2675, 2001. Fine, P. M, Cass, G. R., Simoneit, B. R. T.: Chemical characterization of fine particle emissions from the fireplace combustion of woods grown in the Southern United States, Environ. Sci. Technol., 36, 1442–1451, 2002a. Fine, P. M., Cass, G. R., and Simoneit, B. R. T.: Organic compounds in biomass smoke from residential wood combustion: Emissions characterization at a continental scale, J. Geophys. Res.-Atmos., 107, 8349, doi:10.1029/2001JD000661, 2002b. Fine, P. M., Cass, G. R., and Simoneit, B. R. T.: Chemical characterization of fine particle emissions from the fireplace combustion of wood types grown in the Midwestern and Western United States, Environ. Eng. Sci., 21, 387–409, 2004. Forsberg, B., Hansson, H. C., Johansson, C., Areskoug, H., Persson, K., and Jarvholm B.: Comparative health impact assessment of local and regional particulate air pollutants in Scandinavia, Ambio, 34, 11–19, 2005. Gelencsér, A.: Carbonaceous aerosol, Springer, Dordrecht, p. 350, 2004. Gelencsér, A., May, B., Simpson, D., Sánchez-Ochoa, A., Kasper-Giebl, A., Puxbaum, H., Caseiro, A., Pio, C., and Legrand, M.: Source apportionment of PM$_2.5$ organic aerosol over Europe: primary/secondary, natural/anthropogenic, fossil/biogenic origin, J. Geophys. Res., 112, D23S04, doi: 10.1029/2006JD008094, 2007. Glasius, M., Ketzel, M., Wahlin, P., Jensen, B., Mønster, J., Berkowicz, R., Palmgren, F.: Impact of wood combustion on particle levels in a residential area in Denmark, Atm. Environ, 40, 7115–7124, 2006. Graham, B., Mayol-Bracero, O. L., Guyon, P., Roberts, G. C., Decesari, S. Facchini, M. C., Artaxo, P., Maenhaut, W., Köll, P., and Andreae, M. O.: Water-soluble organic compounds in biomass burning aerosols over Amazonia 1. Characterization by NMR and GC-MS, J. Geophys. Res., 107, 8047, doi:10.1029/2001JD000336, 2002. Gray, H. A., Cass, G. R., Huntzicker, J. J., Heyerdahl, E. K., and Rau, J. A.: Characterization of atmospheric organic and elemental carbon particles concentrations in Los-Angeles, Environ. Sci. Technol., 20, 580–589, 1986. Hagen, L. O. and Haugsbakk, I.: Monitoring of nitrogen oxides and suspended particulates close to two roads in Oslo during the winter season 1999/2000, (in Norwegian) Norwegian Institute for Air Research, Kjeller, NILU OR 32/2000, 109 pp., 2000. Haugsbakk, I.: Developing project for dust monitoring. Part 3. Monitoring for tests of models, (in Norwegian) Bergen, Spring 1994, Norwegian Institute for Air Research, Kjeller, NILU OR 38/94, 69 pp., 1994. Hedberg, E., Johansson, C., Johansson, L., Swietlicki, E., and Brorström-Lundén, E.: Is levoglucosan a suitable quantitative tracer for wood burning? Comparison with receptor modeling on trace elements in Lycksele, Sweden, J. Air Waste Man. Assoc., 56, 1669–1678, 2006. Hoek, G., Brunekreef, B., Goldbohm, S., Fischer, P., and van den Brandt, P. A.: Association between mortality and indicators of traffic-related air pollution in the Netherlands: A cohort study, Lancet, 360, 1203–1209, 2002. Hopke, P. K., Xie, Y., Raunemaa, T., Biegalski, S., Landsberger, S., Maenhaut, W., Artaxo, P., and Cohen, D.: Characterization of the gent stacked filter unit PM$_10$ sampler, Aerosol Sci. Tech., 27, 726–735, 1997. IPCC: Climate change 2001: The scientific basis. Contribution of working group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Houghton, J. T., Ding, Y., Griggs, D. J., Noguer, M., van der Linden, P. J., Dai, X., Maskell, K., Johnson, C. A., Cambridge University Press, Cambridge, UK and New York, NY, USA, 881 pp., 2001. Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, 2005. Kawamura, K. and Kaplan, I.: Motor exhaust emissions as a primary source for dicarboxylic acids in Los Angeles ambient air, Environ. Sci. Technol., 21, 105–110, 1987. Kawamura, K. and Ikushima, K.: Seasonal-changes in the distribution of dicarboxylic-acids in the urban atmosphere, Environ. Sci. Technol., 27, 2227–2235, 1993. Kirchstetter, T. W., Corrigan, C. E., and Novakov, T.: Laboratory and field investigation of the adsorption of gaseous organic compounds onto quartz filters, Atmos. Environ., 35, 1663–1671, 2001. Kiss, G., Varga, B., Galambos, I., and Ganszky, I.: Characterization of water-soluble organic matter isolated from atmospheric fine aerosol, J. Geophys. Res., 107, 8339, doi:10.1029/2001JD000603, 2002. Klouda, G. A., Filliben, J. J., Parish, H. J., Chow, J. J., Watson, J. G., and Cary, R. A.: Reference material 8785: Air particulate matter on filter media, Aerosol Sci. Technol., 39, 173–183, 2005. Künzli, N., Kaiser, R., Medina, S., Studnicka, M., Chanel, O., Filliger, P., Herry, M., Horak, F., Puybonnieux-Texier, V., Quenel, P., Schneider, J., Seethaler, R., Vergnaud, J. C., and Sommer, H.: Public health impact of outdoor and traffic-related air pollution: a European assessment, Lancet, 356, 795–801, 2000. Mader, B. T., Yu, J. Z., Xu, J. H., Li, Q. F., Wu, W. S., Flagan, R. C., and Seinfeld, J. H.: Molecular composition of the water-soluble fraction of atmospheric carbonaceous aerosols collected during ACE-Asia, J. Geophys. Res., 109, D06206, doi: 10.1029/2003JD004105, 2004. Malm, W. C., Schichtel, B. A., Pitchford, M. L., Ashbaugh, L. L., and Eldred, R. A.: Spatial and monthly trends in speciated fine particle concentration in the United States, J. Geophys. Res., 109, D03306, doi:10.1029/2003JD003739, 2004. Marsteen, L. and Schaug., J.: A PM$_10$ intercomparison exercise in Norway. Norwegian Institute for Air Research, Kjeller, NILU OR 41/2007, 67 pp., 2007. Mazzoleni, L., Zielinska, B., and Moosmuller, H.: Emissions of levoglucosan, methoxy phenols, and organic acids from prescribed burns, laboratory combustion of wildland fuels, and residential wood combustion, Environ. Sci. Technol., 41, 2115–2122, 2007. McDonald, J. D., Eide, I., Seagrave, J., Zielinska, B., Whitney, K., Lawson, D. R., and Mauderly, J. L.: Relationship between composition and toxicity of motor vehicle emission samples, Environ. Health Persp., 112, 1527–1538, 2004. McDow, S. R. and Huntzicker, J. J.: Vapor adsorption artifact in the sampling of organic aerosol: face velocity effects, Atmos. Environ., 24A, 2563–2571, 1990. Metzger, K. B., Tolbert, P. E., Klein, M., Peel, J. L., Flanders, W. D., Todd, K., Mulholland, J. A., Ryan, P. B., and Frumkin, H.: Ambient air pollution and cardiovascular emergency department visits, Epidemiology, 15, 46–56, 2004. Novakov, T. and Corrigan, C. E.: Cloud condensation nucleus activity of the organic component of biomass smoke particles, Geophys. Res. Lett., 23, 2141–2144, 1996. Novakov, T. and Penner, J. E.: Large contribution of organic aerosols to cloud condensation nuclei concentrations, Nature, 365, 823–826, 1993. Nolte, C. G., Schauer, J. J., Cass, G. R., and Simoneit, B. R. T.: Highly polar organic compounds present in wood smoke and in the ambient atmosphere, Environ. Sci. Technol., 35, 1912–1919, 2001. Putaud, J.-P., Raes, F., Van Dingenen, R., Brüggemann, E., Facchini, M. C., Decesari, S., Fuzzi, S., Gehrig, R., Hüglin, C., Laj, P., Lorbeer, G., Maenhaut, W., Mihalopoulos, N., Müller, K., Querol, X., Rodriguez, S., Schneider, J., Spindler, G., ten Brink, H., Tørseth, K., and Wiedensohler, A.: A European aerosol phenomenology – 2: Chemical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe, Atm. Environ., 38, 2579–2595, 2004. Puxbaum, H. Caseiro, A., Sánchez-Ochoa, Kasper-Giebl, A., Claeys, M., Gelencsér, A., Legrand, M., Preunkert, S., and Pio, C. A.: Levoglucosan levels at background sites in Europe for assessing the impact of biomass combustion on the European, aerosol background, J. Geophys. Res., 112, D23S05, doi:10.1029/2006JD008114, 2007. Ricard, V., Jaffrezo, J. L., Kerminen, V. M., Hillamo, R. E., Sillanpaa, M., Ruellan, S., Liousse, C., and Cachier, H.: Two years of continuous aerosol measurements in northern Finland, J. Geophys. Res., 107, 4129, doi:10.1029/2001JD000952, 2002. Ruellan, S. and Cachier, H.: Characterisation of fresh particulate vehicular exhaust near a Paris high flow road, Atmos. Environ., 35, 453–468, 2001. Saarikoski, S., Sillanpaa, M., Sofiev, M., Timonen, H., Saarnio, K., Teinela, K., Karppinen, A., Kukkonen, J., and Hillamo, R.: Chemical composition of aerosols during a major biomass burning episode over northern Europe in spring 2006: Experimental and modelling assessments, Atmos. Environ., 41, 3577–3589, 2007. Sandradewi, J., Prevot, A. S. H., Alfarra, M. R., Szidat, S., Wehrli, M. N., Ruff, M., Weimer. S., Lanz, Weingartner, E., Perron, N., and Caseiro, A., Kasper-Giebl, A., Puxbaum, H., Wacker, L., and Baltensperger, U.: Comparison of several wood smoke markers and source apportionment methods for wood burning particulate mass, Atmos. Chem. Phys. Discuss., 8, 8091–8118, 2008. Schauer, J., Kleeman, M., Cass, G., and Simoneit, B.: Measurement of emissions from air pollution sources. 3. C1-C29 organic compounds from fireplace combustion of wood, Environ. Sci. Technol., 35, 1716–1728, 2001. Schkolnik, G. and Rudich, Y.: Detection and quantification of levoglucosan in atmospheric aerosols – review, Anal. Bioanal. Chem., 385, 26–33, doi:10.1007/s00216-005-0168-5, 2006. Schmidl, C., Marr, I. L., Caseiro, A., Kotianova, P., Berner, A., Bauer, H., Kasper-Giebl, A., and Puxbaum, H.: Chemical characterisation of fine particle emissions from wood stove combustion of common woods growing in mid-European Alpine regions, Atmos. Environ., 42, 126–141, 2008. Sillanpaa, M., Hillamo, R., Saarikoski, S., Frey, A., Pennanen, A., Makkonen, U., Spolnik, Z., Van Grieken, R., Branis, M., Brunekreef, B., Chalbot, M. C., Kuhlbusch, T., Sunyer, J., Kerminen, V. M., Kulmala, M., and Salonen, R. O.: Chemical composition and mass closure of particulate matter at six urban sites in Europe, Atmos. Environ., 40, S212–S223, 2006. Simoneit, B. R. T., Schauer, J. J., Nolte, C. G., Oros, D. R., Elias, V. O., Fraser, M. P., Rogge, W. F., and Cass., G. R.: Levoglucosan, a tracer for cellulose in biomass burning and atmospheric particles, Atmos. Environ., 33, 173–182, 1999. Simpson, D., Yttri, K. E., Klimont, Z., Kupiainen, K., Caseiro, A., Gelencsér, A., Pio, C., and Legrand, M.: Modeling carbonaceous aerosol over Europe. Analysis of the CARBOSOL and EMEP EC/OC campaigns, J. Geophys. Res., 112, D23S14, doi:10.1029/2006JD008114, 2007. Stohl, A., Berg, T., Burkhart, J. F., Fjæraa, A. M., Forster, C., Herber, A., Hov, Ø., Lunder, C., McMillan, W. W., Oltmans, S., Shiobara, M., Simpson, D., Solberg, S., Stebel, K., Ström, J., Tørseth, K., Treffeisen, R., Virkkunen, K., and Yttri, K. E.: Arctic smoke – record high air pollution levels in the European Arctic due to agricultural fires in Eastern Europe, Atmos. Chem. Phys., 7, 511–534, 2007. Subramanian, R., Khlystov, A. Y., Cabada, J. C., and Robinson, A. L.: Positive and negative artifacts in particulate organic carbon measurements with denuded and undenuded sampler configurations, Aerosol Sci. Techn., 38(S1), 27–48, 2004. Turpin, B. J., Huntzicker, J. J., and Hering S. V.: Investigation of organic aerosol sampling artifacts in the Los Angeles basin, Atmos. Environ., 28, 3061–3071, 1994. Turpin, B. J. and Lim, H.-J.: Species contributions to PM$_2.5$ mass concentrations: Revisiting common assumptions for estimating organic mass, Aerosol Sci. Techn., 35, 602–610, 2001. Turpin, B. J., Saxena, P., and Andrews, E.: Measuring and simulating particulate organics in the atmosphere: problems and prospects, Atmos. Environ., 34, 2983–3013, 2000. Viidanoja, J., Sillanpää, M., Laakia, J., Kerminen, V.-M., Hillamo, R., Aarnio, P., and Koskentalo, T.: Organic and black carbon in PM$_2.5$ and PM$_10$: 1 year of data from an urban site in Helsinki, Finland, Atmos. Environ., 36, 3183–3193, 2002. WHO: Health aspects of air pollution with particulate matter, ozone and nitrogen dioxide. Report on a WHO working group, Bonn, Germany 13–15 January 2003, World Health Organization, Geneva, 94 pp., 2003. Yttri, K. E., Aas, W., Bjerke, A., Cape, J. N., Cavalli, F., Ceburnis, D., Dye, C., Emblico, L., Facchini, M. C., Forster, C., Hanssen, J. E., Hansson, H. C., Jennings, S. G., Maenhaut, W., Putaud. J. P., and Tørseth, K.: Elemental and organic carbon in PM$_10$: A one year measurement campaign within the European monitoring and Evaluation Programme EMEP, Atmos. Chem. Phys., 7, 5711–5725, 2007a. Yttri, K. E., Dye, C., and Kiss, G.: Ambient aerosol concentrations of sugars and sugar-alcohols at four different sites in Norway, Atmos. Chem. Phys., 7, 4267–4279, 2007b. Yttri, K. E., Dye, C., Slørdal, L. H., and Braathen, O.-A.: Quantification of monosaccharide anhydrides by negative electrospray HPLC/HRMS-TOF – Application to aerosol samples from an urban and a suburban site influenced by small scale wood burning, J. Air Waste Manage., 55, 1169–1177, 2005. Zdráhal, Z., Oliveira, J., Vermeylen, R., Claeys, M., and Maenhaut, W.: Improved method for quantifying levoglucosan and related monosaccharide anhydrides in atmospheric aerosols and application to samples from urban and tropical locations, Environ. Sci. Technol., 36, 747–757, 2002. Zappoli, S., Andracchio, A., Fuzzi, S., Facchini, M. C., Gelencsér, A., Kiss, G., Krivacsy, Z., Molnar, A., Meszaros, E., Hansson, H. C., Rosman, K., and Zebuhr, Y.: Inorganic, organic and macromolecular components of fine aerosol in different areas of Europe in relation to their water solubility, Atmos. Environ., 33, 2733–2743, 1999.