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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics Discussions</journal_title>
		<journal_url>www.atmos-chem-phys-discuss.net</journal_url>
		<issn>1680-7367</issn>
		<eissn>1680-7375</eissn>
		<volume_number>8</volume_number>
		<issue_number>5</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/acpd-8-17237-2008</doi>
	<article_url>http://www.atmos-chem-phys-discuss.net/8/17237/2008/</article_url>
	<abstract_html>http://www.atmos-chem-phys-discuss.net/8/17237/2008/acpd-8-17237-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys-discuss.net/8/17237/2008/acpd-8-17237-2008.pdf</fulltext_pdf>
	<start_page>17237</start_page>
	<end_page>17256</end_page>
	<publication_date>2008-09-11</publication_date>
	<article_title content_type="html">The Cloud Condensation Nuclei (CCN) properties of 2-methyltetrols and C3–C6 polyols from osmolality and surface tension measurements</article_title>
	<authors>
		<author numeration="1" affiliations="1,3">
			<name>S. Ekström</name>
		</author>
		<author numeration="2" affiliations="1,3">
			<name>B. Nozière</name>
			<email>barbara.noziere@itm.su.se</email>
		</author>
		<author numeration="3" affiliations="2">
			<name>H.-C. Hansson</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Department of Meteorology, Stockholm Univ., Stockholm, Sweden</affiliation>
		<affiliation numeration="2" content_type="html">Department of Applied Environmental Science (ITM), Stockholm University, Stockholm, Sweden</affiliation>
		<affiliation numeration="3" content_type="html">now at: Department of Applied Environmental Science (ITM), Stockholm University, Stockholm, Sweden</affiliation>
	</affiliations>
	<abstract content_type="html">A significant fraction of the organic material in aerosols is made of highly
soluble compounds such as sugars (mono- and polysaccharides) and polyols,
including the 2-methyltetrols, methylerythritol and methyltreitol. The high
solubility of these compounds has brought the question of their potentially
high CCN efficiency. For the 2-methyltetrols, this would have important
implications for cloud formation at global scale because they are thought to
be produced by the atmospheric oxidation of isoprene. To investigate this
question, the complete Köhler curves for C3–C6 polyols and the
2-methyltetrols have been determined experimentally from osmolality and
surface tension measurements. Contrary to what expected, none of these
compounds displayed a critical supersaturation lower than those of inorganic
salts or organic acids. Their Raoult terms show that this limited CCN
efficiency is due to their absence of dissociation in water, this in spite
of slight surface-tension effects for the 2-methyltetrols. Thus, compounds
such as sugars and polyols would not contribute more to cloud formation in
the atmosphere than any other organic compounds studied so far. In
particular, the presence of 2-methyltetrols in aerosols would not
particularly enhance cloud formation in the atmosphere, contrary to what has
been suggested.</abstract>
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