Atmos. Chem. Phys. Discuss., 8, 11685-11754, 2008
www.atmos-chem-phys-discuss.net/8/11685/2008/
doi:10.5194/acpd-8-11685-2008
© Author(s) 2008. This work is distributed
under the Creative Commons Attribution 3.0 License.
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Gas phase precursors to anthropogenic secondary organic aerosol: detailed observations of 1,3,5-trimethylbenzene photooxidation
K. P. Wyche1, P. S. Monks1, A. M. Ellis1, R. L. Cordell1, A. E. Parker1, C. Whyte1, A. Metzger2, J. Dommen2, J. Duplissy2, A. S. H. Prevot2, U. Baltensperger2, A. R. Rickard3, and F. Wulfert4
1Atmospheric Chemistry, Dept. of Chemistry, Univ. of Leicester, Leicester, LE1 7RH, UK
2Laboratory of Atmospheric Chemistry, Paul Scherrer Institut, 5232, Villigen, Switzerland
3National Centre for Atmospheric Science, University of Leeds, Leeds, LS2 9JT, UK
4Division of Food Sciences, University of Nottingham, Sutton Bonington Campus, Loughborough, LE12 5RD, UK

Abstract. A series of photooxidation experiments were conducted in an atmospheric simulation chamber in order to investigate the secondary organic aerosol (SOA) formed from the anthropogenic model gas phase precursor, 1,3,5-trimethylbenzene. Alongside specific aerosol measurements, comprehensive gas phase measurements, primarily by chemical ionisation reaction time-of-flight mass spectrometry (CIR-TOF-MS), were carried out to provide detailed insight into the composition and behaviour of the organic components of the gas phase matrix during SOA formation. An array of gas phase organic compounds was measured during the oxidation process, including several previously unmeasured primary bicyclic compounds possessing various functional groups. Analysis of results obtained during this study implies that these peroxide bicyclic species along with a series of furanones and organic acids contribute to SOA growth. The effect of varying the VOC/NOx ratio on SOA formation was explored, as was the effect of acid seeding. It was found that low NOx conditions favour more rapid aerosol formation and a higher aerosol yield, a finding that points towards a role for organic peroxides in the nucleation process and SOA growth.

Citation: Wyche, K. P., Monks, P. S., Ellis, A. M., Cordell, R. L., Parker, A. E., Whyte, C., Metzger, A., Dommen, J., Duplissy, J., Prevot, A. S. H., Baltensperger, U., Rickard, A. R., and Wulfert, F.: Gas phase precursors to anthropogenic secondary organic aerosol: detailed observations of 1,3,5-trimethylbenzene photooxidation, Atmos. Chem. Phys. Discuss., 8, 11685-11754, doi:10.5194/acpd-8-11685-2008, 2008.
 
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