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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-7-9899-2007</article-id>
<title-group>
<article-title>Nitrogen compounds and ozone in the stratosphere: comparison of MIPAS satellite data with the Chemistry Climate Model ECHAM5/MESSy1</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Brühl</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Steil</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stiller</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Funke</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Jöckel</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Max-Planck-Institute for Chemistry, Mainz, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institute for Meteorology and Climate Research, Forschungszentrum Karlsruhe, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Instituto de Astrof&amp;#x00ED;sica de Andaluc&amp;#x00ED;a, Granada, Spain</addr-line>
</aff>
<pub-date pub-type="epub">
<day>09</day>
<month>07</month>
<year>2007</year>
</pub-date>
<volume>7</volume>
<issue>4</issue>
<fpage>9899</fpage>
<lpage>9924</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/7/9899/2007/acpd-7-9899-2007.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/7/9899/2007/acpd-7-9899-2007.pdf</self-uri>
<abstract>
<p>The chemistry climate model ECHAM5/MESSy1 (E5/M1) in a
setup extending from the surface to 80 km with a vertical resolution of
about 600 m near the tropopause with nudged tropospheric meteorology allows
a direct comparison with satellite data of chemical species at the same time
and location. Here we present results out of a transient 10 years simulation
for the period of the Antarctic vortex split in September 2002, where data of
MIPAS on the ENVISAT-satellite are available. For the first time this
satellite instrument opens the opportunity, to evaluate all stratospheric
nitrogen containing species simultaneously with a good global coverage,
including the source gas N&lt;sub&gt;2&lt;/sub&gt;O which allows an estimate for NO&lt;sub&gt;x&lt;/sub&gt;-production in the stratosphere. 
We show correlations between simulated and observed species in the altitude region between 10 and 50 hpa for
different latitude belts, together with the Probability Density Functions
(PDFs) of model results and observations. This is supplemented by global
charts on pressure levels showing the satellite data and the simulated data
sampled at the same time and location. We demonstrate that the model in most
cases captures the partitioning in the nitrogen family, the diurnal cycles
and the spatial distribution within experimental uncertainty. There appears
to be, however, a problem to reproduce the observed nighttime partitioning
between N&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt; and NO&lt;sub&gt;2&lt;/sub&gt; in the middle stratosphere.</p>
</abstract>
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