Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 7 3 2007 10.5194/acpd-7-7399-2007 http://www.atmos-chem-phys-discuss.net/7/7399/2007/ http://www.atmos-chem-phys-discuss.net/7/7399/2007/acpd-7-7399-2007.html http://www.atmos-chem-phys-discuss.net/7/7399/2007/acpd-7-7399-2007.pdf 7399 7450 2007-05-30 Seasonal variation of ozone deposition to a tropical rain forest in southwest Amazonia U. Rummel udo.rummel@dwd.de C. Ammann G. A. Kirkman M. A. L. Moura T. Foken M. O. Andreae F. X. Meixner Max Planck Institute for Chemistry, Biogeochemistry Dept., 55020 Mainz, Germany Departamento de Meteorologia, Universidade Federal de Alagoas, Macei, Brazil University of Bayreuth, Micrometeorology Dept., 95440 Bayreuth, Germany now at: Richard Assmann Observatory Lindenberg, German Meteorological Service, Germany now at: Agroscope ART, Air Pollution and Climate Group, 8046 Zürich, Switzerland now at: United Nations Framework Convention on Climate Change, 53179 Bonn, Germany Within the project EUropean Studies on Trace gases and Atmospheric CHemistry as a contribution to Large-scale Biosphere–atmosphere experiment in Amazonia (LBA-EUSTACH), we performed tower-based eddy covariance measurements of O3 flux above an Amazonian primary rain forest at the end of the wet and dry seasons. Ozone deposition revealed distinct seasonal differences in the magnitude and diel variation. In the wet season, the rain forest was an effective O3 sink with a mean daytime (midday) maximum deposition velocity of 2.3 cm s−1, and a corresponding O3 flux of –11 nmol m−2 s−1. At the end of the dry season, the ozone mixing ratio was about four times higher (up to maximum values of 80 ppb) than in the wet season, as a consequence of strong regional biomass burning activity. However, the typical maximum daytime deposition flux was very similar to the wet season. This results from a strong limitation of daytime O3 deposition due to reduced plant stomatal aperture as a response to large values of the specific humidity deficit. As a result, the average midday deposition velocity in the dry burning season was only 0.5 cm s−1. The large diel ozone variation caused large canopy storage effects that masked the true diel variation of ozone deposition mechanisms in the measured eddy covariance flux, and for which corrections had to be made. In general, stomatal aperture was sufficient to explain the largest part of daytime ozone deposition. However, during nighttime, chemical reaction with nitrogen monoxide (NO) was found to contribute substantially to the O3 sink in the rain forest canopy. Further contributions were from non-stomatal plant uptake and other processes that could not be clearly identified. Measurements, made simultaneously on a 22 years old cattle pasture enabled the spatially and temporally direct comparison of O3 dry deposition values from this site with typical vegetation cover of deforested land in southwest Amazonia to the results from the primary rain forest. The mean ozone deposition to the pasture was found to be systematically lower than that to the forest by 30% in the wet and 18% in the dry season. Altimir, N., Kolari, P., Tuovinen, J.-P., Vesala, T., Bäck, J., Suni, T., Kulmala, M., and Hari, P.: Foliage surface ozone deposition: a role for surface moisture?, Biogeosciences, 3, 209–228, 2006. 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