Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 7 2 2007 10.5194/acpd-7-5013-2007 http://www.atmos-chem-phys-discuss.net/7/5013/2007/ http://www.atmos-chem-phys-discuss.net/7/5013/2007/acpd-7-5013-2007.html http://www.atmos-chem-phys-discuss.net/7/5013/2007/acpd-7-5013-2007.pdf 5013 5051 2007-04-11 Vertical profiles of lightning-produced NO₂ enhancements in the upper troposphere observed by OSIRIS C. E. Sioris christopher.sioris@ec.gc.ca C. A. McLinden R. V. Martin B. Sauvage C. S. Haley N. D. Lloyd E. J. Llewellyn P. F. Bernath C. D. Boone S. Brohede C. T. McElroy Experimental Studies Sect., Environment Canada, Toronto, ON, Canada Institute of Space and Atmospheric Studies, University of Saskatchewan, Saskatoon, SK, Canada Atomic and Molecular Physics Division, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA, USA Department of Physics and Atmospheric Science, Dalhousie University, Halifax, NS, Canada Centre for Research in Earth and Space Science, York University, Toronto, Ontario, Canada Department of Chemistry, University of Waterloo, Waterloo, ON, Canada Department of Chemistry, University of York, Heslington, York, UK Department of Radio and Space Science, Chalmers University of Technology, Göteborg, Sweden The purpose of this study is to perform a global search of the upper troposphere (z≥10 km) for enhancements of nitrogen dioxide and determine their sources. We have searched two years (May 2003–May 2005) of OSIRIS (Optical Spectrograph and Infrared Imager System) operational NO₂ data (version 2.3/2.4) to find large enhancements in the observations by comparing concentrations with those predicted by a photochemical model and by identifying local maxima in NO₂ volume mixing ratio. We find that lightning is the main production mechanism responsible for the large enhancements in OSIRIS NO₂ observations as expected. Similar patterns in the abundances and spatial distribution of the NO₂ enhancements are obtained by perturbing the lightning within the GEOS-Chem 3-dimensional chemical transport model. In most cases, the presence of lightning is confirmed with coincident imagery from LIS (Lightning Imaging Sensor) and the spatial extent of the NO₂ enhancement is mapped using nadir observations of tropospheric NO₂ at high spatial resolution from SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric Chartography) and OMI (Ozone Monitoring Instrument). The combination of the lightning and chemical sensors allows us to investigate globally the role of lightning to the abundance of NO₂ in the upper troposphere (UT). This is the first application of satellite-based limb scattering to study upper tropospheric NO₂. The spatial and temporal distribution of NO₂ enhancements from lightning (May 2003–May 2005) is investigated. The NO₂ from lightning generally occurs at 12 to 13 km more frequently than at 10 to 11 km. This is consistent with the notion that most of the NO₂ is forming and persisting near the cloud top altitude in the tropical upper troposphere. The latitudinal distribution is mostly as expected. In general, the thunderstorms exhibiting weaker vertical development (e.g. 11≤z≤13 km) extend latitudinally as far poleward as 45° but the thunderstorms with stronger vertical development (z≥14 km) tend to be located within 33° of the equator. There is also the expected hemispheric asymmetry in the frequency of the NO₂ enhancements, as most were observed in the Northern Hemisphere for the period analyzed. Bernath, P. F, McElroy, C. T., Abrams, M. C., et al.: Atmospheric Chemistry Experiment (ACE): Mission overview, Geophys. Res. Lett., 32, L15S01, doi:10.1029/2005GL022386, 2005. Bertram, T. H., Perring, A. E., Wooldridge, P. J., et al.: Direct measurements of the convective recycling of the upper troposphere, Science, 315, 816–820, 2007. Bey, I., Jacob, D. J., Yantosca, R. M., Logan, J. A., Field, B., Fiore, A. M., Li, Q., Liu, H., Mickley, L. J., and Schultz, M.: Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, J. Geophys. Res., 106, 23 073–23 096, 2001. Bovensmann, H., Burrows, J. P., Buchwitz, M., Frerick, J., Rozanov, S., No\"el, V. V., Chance, K. V., and Goede, A. P. H.: SCIAMACHY: Mission objectives and measurement modes, J. Atmos. Sci., 56, 127–150, 1999. Brohede, S. M., Haley, C. S., McLinden, C. A., et al.: Validation of Odin/OSIRIS stratospheric NO$_2 $ profiles, J. Geophys. Res., in press, 2007. Bucsela, E. J., Celarier, E. A., Wenig, M. O., Gleason, J. F., Veefkind, J. P., Boersma, K. F., and Brinksma, E. J.: Algorithm for NO₂ vertical column retrieval from the Ozone Monitoring Instrument, IEEE Trans. Geosci. Remote Sens., 44, 1245–1258, 2006. Chahine, M. T.: Inverse problems in radiative transfer: Determination of atmospheric parameters, J. Atmos. Sci., 27, 960–967, 1970. Choi, Y., Wang, Y., Zeng, T., Martin, R. V., Kurosu, T. P., and Chance, K.: Evidence of lightning NO_x and convective transport of pollutants in satellite observations over North America, Geophys. Res. Lett., 32, L02805, doi:10.1029/2004GL021436, 2005. Christian, H. J., Blakeslee, R. J., Boccippio, D. J., et al.: Global frequency and distribution of lightning as observed from space by the Optical Transient Detector, J. Geophys. Res., 108(D1), 4005, doi:10.1029/2002JD002347, 2003. Funke, B., López-Puertas, M., von Clarmann, T., et al.: Retrieval of stratospheric NO_x from 5.3 and 6.2 mm nonlocal thermodynamic equilibrium emissions measured by Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat, J. Geophys. Res., 110, D09302, doi:10.1029/2004JD005225, 2005. Gordley, L. L., Russell III, J. M., Mickley, L. J., et al.: Validation of nitric oxide and nitrogen dioxide measurements made by the Halogen Occultation Experiment for UARS platform, J. Geophys. Res., 101, 10 241–10 266, 1996. Haley, C. S., Brohede, S. M., Sioris, C. E., Griffioen, E., Murtagh, D. P., McDade, I. C., Eriksson, P., Llewellyn, E. J., Bazureau, A., and Goutail, F.: Retrieval of stratospheric O₃ and NO₂ profiles from Odin Optical Spectrograph and Infrared Imager System (OSIRIS) limb-scattered sunlight measurements, J. Geophys. Res., 109, D16303, doi:10.1029/2004JD004588, 2004. Heirtzler, J. R.: The future of the South Atlantic anomaly and implications for radiation damage in space, J. Atmos. Solar-Terr. Phys., 64, 1701–1708, 2002. Hudman, R. C., Jacob, D. J., Turquety, S., et al.: Surface and lightning sources of nitrogen oxides over the United States: magnitudes, chemical evolution, and outflow, J. Geophys. Res., in press, 2007. Intergovernmental Panel on Climate Change, Climate change 2001: The scientific basis, 881 pp., Cambridge University Press, Cambridge, UK, 2001. Jaeglé, L., Jacob, D. J., Wang, Y., Weinheimer, A. J., Ridley, B. A., Campos, T. L., Sachse, G. W., and Hagen, D. E.: Sources and chemistry of NO_x in the upper troposphere over the United States, Geophys. Res. Lett., 25, 1705–1708, 1998. Kalnay, E., Kanamitsu, M., Kistler, R., et al.: The NCEP/NCAR 40-year reanalysis project, Bull. Amer. Meteorol. Soc., 77, 437–470, 1996. Koelemeijer, R. B. A., de Haan, J. F., and Stammes, P.: A database of spectral surface reflectivity in the range 335–772 nm derived from 5.5 years of GOME observations, J. Geophys. Res., 108(D2), 4070, doi:10.1029/2002JD002429, 2003. Lamarque, J. F., Brasseur, G. P., Hess, P. G., and Mueller, J. F.: Three-dimensional study of the relative contributions of the different nitrogen sources in the troposphere, J. Geophys. Res., 101, 22 955–22 968, 2006. Levelt, P. F., van den Oord, G. H. J., Dobber, M. R., Mälkki, A., Visser, H., de Vries, J., Stammes, P., Lundell, J., and Saari, H.: The Ozone Monitoring Instrument, IEEE Trans. Geosci. Remote Sens., 44, 1093–1101, 2006. Llewellyn, E. J., Lloyd, N. D., Degenstein, D. A., et al.: The OSIRIS instrument on the Odin satellite, Can. J. Phys., 82, 411–422, 2004. Martin, R. V., Sauvage, B., Folkins, I., Sioris, C. E., Boone, C., Bernath, P., Ziemke, J.: Space-based constraints on the production of nitric oxide by lightning, J. Geophys. Res., in press, 2007. Martin, R. V., Sioris, C. E., Chance, K., Ryerson, T. B., Bertram, T. H., Wooldridge, P. J., Cohen, R. C., Neuman, J. A., Swanson, A. L., and Flocke, F. M.: Evaluation of space-based constraints on global nitrogen oxide emissions with regional aircraft measurements over and downwind of eastern North America, J. Geophys. Res., 111, D15308, doi:10.1029/2005JD006680, 2006. McLinden, C. A., McConnell, J. C., Griffioen, E., and McElroy, C. T.: A vector radiative-transfer model for the Odin/OSIRIS project, Can. J. Phys. 80, 375–393, 2002. McLinden, C. A., Olsen, S. C., Hannegan, B. J., Wild, O., Prather, M. J., and Sundet, J.: Stratospheric Ozone in 3-D Models: A simple chemistry and the cross-tropopause flux, J. Geophys. Res., 105, 14 653–14 665, 2000. McLinden, C. A., Haley, C. S., and Sioris, C. E.: Diurnal effects in limb scatter observations, J. Geophys. Res., 111, D14302, doi:10.1029/2005JD006628, 2006. Molinari, J., Moore, P. K., Idone, V. P., Henderson, R. W., and Saljoughy, A. B.: Cloud-to-ground lightning in Hurricane Andrew, J. Geophys. Res., 99(D8), 16 665–16 676, 1994. Murtagh, D., Frsik, U. , Merino, F., et al.: An overview of the Odin atmospheric mission, Can. J. Phys. 80, 309–319, 2002. Nesbitt, S. W., Zhang, R., and Orville, R. E.: Seasonal and global NO_x production by lightning estimated from the Optical Transient Detector (OTD), Tellus, 52B, 1206–1215, 2000. Pickering, K. E., Wang, Y. S., Tao, W. K., Price, C., and Mueller, J. F.: Vertical distributions of lightning NO_x for use in regional and global chemical transport models, J. Geophys. Res., 103(D23), 31 203–31 216, 1998. Price, C. and Rind, D.: A simple lightning parameterization for calculating global lightning distributions, J. Geophys. Res., 97, 9919–9933, 1992. Price, C., Penner, J., and Prather, M.: NO$_\rm x $from lightning 1. Global distribution based on lightning physics, J. Geophys. Res., 102, 5929–5941, 1997. Randall, C. E., Harvey, V. L., Manney, G. L., et al.: Stratospheric effects of energetic particle precipitation in 2003–2004, Geophys. Res. Lett., 32, L05802, doi:10.1029/2004GL022003, 2005. Rolph, G. D.: Real-time Environmental Applications and Display sYstem (READY) Website (http://www.arl.noaa.gov/ready/hysplit4.html), NOAA Air Resources Laboratory, Silver Spring, MD, 2003. Sauvage, B., Martin, R. V., van Donkelaar, A., Liu, X., Chance, K., Jaeglé, L., Palmer, P. I., Wu, S., and Fu, T. M.: Remote sensed and in situ constraints on processes affecting tropical tropospheric ozone, Atmos. Chem. Phys., 7, 815–838, 2007. Sioris, C. E., Haley, C. S., McLinden, C. A., et al.: Stratospheric profiles of nitrogen dioxide observed by Optical Spectrograph and Infrared Imager System on the Odin satellite, J. Geophys. Res., 108(D7), 4215, doi:10.1029/2002JD002672, 2003. Sioris, C. E., Kurosu, T. P., Martin, R. V., and Chance, K.: Stratospheric and tropospheric NO2 observed by SCIAMACHY: First results, Adv. Space Res., 34(4), 780–785, 2004. Sioris, C. E., Kovalenko, L. J., McLinden, C. A., et al.: Latitudinal and vertical distribution of bromine monoxide in the lower stratosphere from SCIAMACHY limb scattering measurements, J. Geophys. Res., 111, D14301, doi:10.1029/2005JD006479, 2006. Tomikawa, Y. and Sato, K.,: Trapped waves in the edge region of stratospheric polar vortices, J. Geophys. Res., 108(D2), 4047, doi:10.1029/2002JD002579, 2003. Wang, Y., Jacob, D. J., and Logan, J. A.: Global simulation of tropospheric O3-NO_x-hydrocarbon chemistry, 1. Model formulation, J. Geophys. Res., 103, 10 713–10 726, 1998. World Meteorological Organization: Scientific Assessment of Ozone Depletion: 1998, Geneva, Switzerland, 1999.