Atmos. Chem. Phys. Discuss., 7, 11647-11683, 2007
www.atmos-chem-phys-discuss.net/7/11647/2007/
doi:10.5194/acpd-7-11647-2007
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Volatile organic compound ratios as probes of halogen atom chemistry in the Arctic
A. E. Cavender1, T. A. Biesenthal2,*, J. W. Bottenheim3, and P. B. Shepson1,2,4,5
1Department of Chemistry, Purdue University, West Lafayette, IN, USA
2Department of Chemistry, York University, Toronto, Ontario, Canada
3Science and Technology Branch, Environment Canada, Toronto, Ontario, Canada
4Department of Earth and Atmospheric Science, Purdue University, West Lafayette, IN, USA
5Purdue Climate Change Research Center, Purdue University, West Lafayette, IN, USA
*now at: Sciex, Concord, Ontario, Canada

Abstract. Volatile organic compound concentration ratios can be used as indicators of halogen chemistry that occurs during ozone depletion events in the Arctic during spring. Here we use a combination of modeling and measurements of [acetone]/[propanal] as an indicator of bromine chemistry, and [isobutane]/[n-butane] and [methyl ethyl ketone]/[n-butane] are used to study the extent of chlorine chemistry during four ozone depletion events during the Polar Sunrise Experiment of 1995. Using a 0-D photochemistry model in which the input of halogen atoms is controlled and varied, the approximate ratio of [Br]/[Cl] can be estimated for each ozone depletion event. It is concluded that there must be an additional source of propanal (likely from the snowpack) to correctly simulate the VOC chemistry of the Arctic, and that the ratio of Br atoms to Cl atoms can vary greatly during ozone depletion events.

Citation: Cavender, A. E., Biesenthal, T. A., Bottenheim, J. W., and Shepson, P. B.: Volatile organic compound ratios as probes of halogen atom chemistry in the Arctic, Atmos. Chem. Phys. Discuss., 7, 11647-11683, doi:10.5194/acpd-7-11647-2007, 2007.
 
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