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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics Discussions</journal_title>
		<journal_url>www.atmos-chem-phys-discuss.net</journal_url>
		<issn>1680-7367</issn>
		<eissn>1680-7375</eissn>
		<volume_number>7</volume_number>
		<issue_number>4</issue_number>
		<publication_year>2007</publication_year>
	</journal>
	<doi>10.5194/acpd-7-11621-2007</doi>
	<article_url>http://www.atmos-chem-phys-discuss.net/7/11621/2007/</article_url>
	<abstract_html>http://www.atmos-chem-phys-discuss.net/7/11621/2007/acpd-7-11621-2007.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys-discuss.net/7/11621/2007/acpd-7-11621-2007.pdf</fulltext_pdf>
	<start_page>11621</start_page>
	<end_page>11646</end_page>
	<publication_date>2007-08-08</publication_date>
	<article_title content_type="html">Summertime stratospheric processes at northern mid-latitudes: comparisons between MANTRA balloon measurements and the Canadian Middle Atmosphere Model</article_title>
	<authors>
		<author numeration="1" affiliations="1,2">
			<name>S. M. L. Melo</name>
			<email>stella.melo@space.gc.ca</email>
		</author>
		<author numeration="2" affiliations="6">
			<name>R. Blatherwick</name>
		</author>
		<author numeration="3" affiliations="4">
			<name>J. Davies</name>
		</author>
		<author numeration="4" affiliations="2">
			<name>P. Fogal</name>
		</author>
		<author numeration="5" affiliations="4">
			<name>J. de Grandpré</name>
		</author>
		<author numeration="6" affiliations="3">
			<name>J. McConnell</name>
		</author>
		<author numeration="7" affiliations="4">
			<name>C. T. McElroy</name>
		</author>
		<author numeration="8" affiliations="2">
			<name>C. McLandress</name>
		</author>
		<author numeration="9" affiliations="6">
			<name>F. J. Murcray</name>
		</author>
		<author numeration="10" affiliations="6">
			<name>J. R. Olson</name>
		</author>
		<author numeration="11" affiliations="3">
			<name>K. Semeniuk</name>
		</author>
		<author numeration="12" affiliations="2">
			<name>T. G. Shepherd</name>
		</author>
		<author numeration="13" affiliations="2">
			<name>K. Strong</name>
		</author>
		<author numeration="14" affiliations="4">
			<name>D. Tarasick</name>
		</author>
		<author numeration="15" affiliations="1,5">
			<name>B. J. Williams-Rioux</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Canadian Space Agency, St-Hubert, Quebec, Canada</affiliation>
		<affiliation numeration="2" content_type="html">Department of Physics, University of Toronto, Ontario, Canada</affiliation>
		<affiliation numeration="3" content_type="html">Department of Earth and Space Science and Engineering, York University, Ontario, Canada</affiliation>
		<affiliation numeration="4" content_type="html">Environment Canada, Canada</affiliation>
		<affiliation numeration="5" content_type="html">Department of Atmosphere and Ocean, McGill University, Montreal, Quebec, Canada</affiliation>
		<affiliation numeration="6" content_type="html">Department of Physics and Astronomy, University of Denver, CO, USA</affiliation>
	</affiliations>
	<abstract content_type="html">In this paper we report on a study conducted using the Middle Atmospheric
Nitrogen TRend Assessment (MANTRA) balloon measurements of stratospheric
constituents and temperature and the Canadian Middle Atmosphere Model (CMAM)
in order to evaluate the ability of the model to reproduce the measured
fields and to thereby test our ability to describe mid-latitude summertime
stratospheric processes. The MANTRA measurements used here are vertical
profiles of ozone, temperature, N&lt;sub&gt;2&lt;/sub&gt;O, CH&lt;sub&gt;4&lt;/sub&gt;, HNO&lt;sub&gt;3&lt;/sub&gt;, and HCl
obtained during four campaigns, involving the launch of both ozonesondes and
large balloons from Vanscoy, Saskatchewan, Canada (52&amp;deg; N, 107&amp;deg; W). The
campaigns were conducted in August and September 1998, 2000, 2002 and 2004.
During late summer at mid-latitudes, the stratosphere is close to
photochemical control, providing an ideal scenario for the study reported
here. From this analysis we found that: (1) reducing the value for the
vertical diffusion coefficient in CMAM to a more physically reasonable value
results in the model better reproducing the measured profiles of long-lived
species; (2) the existence of compact correlations among the constituents,
as expected from independent measurements in the literature and from models,
confirms the self-consistency of the MANTRA measurements; and (3) the 1998
ozone measurements show a narrow layer of low ozone centered near 25 km that
is consistent with fossil debris from the polar vortex, suggesting that
localized springtime ozone anomalies can persist through summer, affecting
ozone levels at mid-latitudes.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Appenzeller, C., Weiss, A. K., and Stachclin, J.: North Atlantic Oscillation modulates total ozone trends, Geophys. Res. Lett., 27, 1131&amp;ndash;1134, 2000. </reference>
		<reference numeration="2" content_type="text"> Avallone, L. M. and Prather, M. J.: Tracer-tracer correlations: Three-dimentional model simulations and xomparisons to observations, J. Geophys. Res., 102(D15), 19 233&amp;ndash;19 246, 1997. </reference>
		<reference numeration="3" content_type="text"> Beagley, S. R., Grandpré, J. D., Koshyk, J. N., McFarlane, N. A., and Shepherd, T. G.: Radiative-dynamical climatology of the first-generation Canadian Middle Atmosphere Model, Atmos.-Ocean, 35, 293&amp;ndash;331, 1997. </reference>
		<reference numeration="4" content_type="text"> Birner, T., Sankey, D., and Shepherd, T. G.: The troposphere inversion layer in models and analyses, Geophys. Res. Lett., 33, L14809, doi:10.1029/2006GRL026599, 2006. </reference>
		<reference numeration="5" content_type="text"> Blatherwick, R. D., Murcray, D. G., Murcray, F. H., Murcray, F. J., Goldman, A., Vanasse, G. A., Massie, S. T., and Cicerone, R. J.: Infrared emission measurements of morning N2O5, J. Geophys. Res., 94, 18 337&amp;ndash;18 340, 1989. </reference>
		<reference numeration="6" content_type="text"> Chipperfield, M. P. and Jones, R. L.: Relative influence of atmospheric chemistry and transport on arctic ozone trends, Nature, 400, 551&amp;ndash;554, 1999. </reference>
		<reference numeration="7" content_type="text"> Davies, J., Tarasick, D., McElroy, C. T., Kerr, J. B., Fogal, P. F., and Savastiouk, V.: Evaluation of ECC Ozonesonde Preparation Methods from Laboratory Tests and Field Comparisons using MANTRA. Proc. Quadrennial Ozone Symposium, Sapporo, Japan, 2000. </reference>
		<reference numeration="8" content_type="text"> de Grandpre, J., Sandilands, J. W., McConnell, J. C., Beagley, S. R., Croteau, P. C., and Danilin, M. Y.: Canadian middle atmosphere model: preliminary results from the chemical transport module, Atmos.-Ocean, 35(4), 385&amp;ndash;431, 1997. </reference>
		<reference numeration="9" content_type="text"> Dobson, G. M. B., Harrison, D. N., and Lawrence, J.: Measurements of the amount of ozone in the Earth&apos;s atmosphere and its relation to other geophysical conditions, Proc. R. Soc. London, Ser. A, 110, 660&amp;ndash;693, 1926. </reference>
		<reference numeration="10" content_type="text"> Durry, G. and Hauchecorne, A.: Evidence for long-lived polar vortex air in the mid-latitude summer stratophere from in situ laser diode CH&lt;sub&gt;4&lt;/sub&gt; and H&lt;sub&gt;2&lt;/sub&gt;O measurements, Atmos. Chem. Phys., 5, 1467&amp;ndash;1472, 2005. </reference>
		<reference numeration="11" content_type="text"> Fahey, D. W., Gao, R. S., Carslaw, K. S., et al.: The detection of large HNO3 particles in the winter Arctic stratosphere, Science, 291, 1026&amp;ndash;1031, 2001. </reference>
		<reference numeration="12" content_type="text"> Fairline, T. D., Profitt, M. H., and Webster, C. R.: The contribution of mixing in Lagrangian photochemical predictions of polar ozone loss over the Arctic in summer 1997, J. Geophys. Res., 104, 26 597&amp;ndash;26 609, 1999. </reference>
		<reference numeration="13" content_type="text"> Fioletov, V. and Shepherd, T. G.: Summertime total ozone variations over middle and polar latitudes, Geophys. Res. Lett., 32, L01207, doi:10.1029/2004GL022080, 2005. </reference>
		<reference numeration="14" content_type="text"> Fioletov, V. E. and Shepherd, T. G.: Seasonal persistence of midlatitude total ozone anomalies, Geophys. Res. Lett., 30(7), 1417, doi:10.1029/2002GL016739, 2003. </reference>
		<reference numeration="15" content_type="text"> Fogal, P. F., Blatherwick, R. D., Murcray, F. J., and Olson, J. R.: Infra-red FTS Measurements of CH&lt;sub&gt;4&lt;/sub&gt;, N&lt;sub&gt;2&lt;/sub&gt;O, O&lt;sub&gt;3&lt;/sub&gt;, HNO&lt;sub&gt;3&lt;/sub&gt;, HCl, CFC-11 and CFC-12 from the MANTRA Balloon Campaign, Atmos.-Ocean, 43(4), 351&amp;ndash;359, 2005. </reference>
		<reference numeration="16" content_type="text"> Hadjinicolaou, P., Pyle, A., Chipperfield, P. M., and Kettleborough, J. A.: Effect of interannual meteorological variability on mid-latitude O3, Geophys. Res. Lett., 24, 2993&amp;ndash;2996, 1997. </reference>
		<reference numeration="17" content_type="text"> Hess, P. G. and Holton, J. R.: The origin of temporal variance in long-lived trace constituents in the summer stratosphere, J. Atmos. Sci., 42, 1455&amp;ndash;1463, 1985. </reference>
		<reference numeration="18" content_type="text"> Hood, L. L., McCormack, J. P., and Labitzke, K.: An investigation of dynamical contributions to midlatitude ozone trends in winter, J. Geophys. Res., 102, 13 079&amp;ndash;13 093, 1997. </reference>
		<reference numeration="19" content_type="text"> Kar, J., Trepe, C. R., Thomason, L. W., and Zawodny, J. M.: Observations of layers of ozone vertical profiles from SAGEII (v6.0) measurements, Geophys. Res. Lett., 29(10), 1443&amp;ndash;1446, 2002. </reference>
		<reference numeration="20" content_type="text"> Komhyr, W. D.: Electrochemical concentration cells for gas analysis, Ann. Géophys., 25, 203&amp;ndash;210, 1969. </reference>
		<reference numeration="21" content_type="text"> Langer, J., Barry, B., Klein, U., Sinnhuber, B.-M., Wohltmann, I., and Kunzi, K. F.: Chemical ozone depletion during Arctic winter 1997/98 derived from ground based millimeter-wave observations, Geophys. Res. Lett., 26(5), 599&amp;ndash;602, 1999. </reference>
		<reference numeration="22" content_type="text"> Loewenstein, M., Podolske, J. R., Fahey, D. W., Woodbridge, E. L., Tin, P., Weaves, A., Newman, P. A., Strahan, S. E., Kawa, S. R., Schoeberl, M. R., and Lait, L. R.: New observations of the NOy/N2O correlation in the lower stratosphere, Geophys. Res. Lett., 20(22), 2531&amp;ndash;2534, 1993. </reference>
		<reference numeration="23" content_type="text"> Michelsen, H. A., Manney, G. L., and Gunson, M. R.: Correlations of stratospheric abundances of NO&lt;sub&gt;y&lt;/sub&gt;, O&lt;sub&gt;3&lt;/sub&gt;, N&lt;sub&gt;2&lt;/sub&gt;O, and CH&lt;sub&gt;4&lt;/sub&gt; derived from ATMOS measurements, J. Geophys. Res, 103(D21), 28 347&amp;ndash;28 359, 1998. </reference>
		<reference numeration="24" content_type="text"> Millard, G. A., Lee, A. M., and Pyle, J. A.: A model study of the connection between polar and midlatitude ozone loss in the Northern Hemisphere lower stratosphere, J. Geophys. Res., 108(D5), 8323, doi:10.1029/2001JD000899, 2003. </reference>
		<reference numeration="25" content_type="text"> Murcray, F. J., Goldman, A., Murcray, D. G., Cook, G. R., van-Allen, J. W., and Blatherwick, R. D.: Identification of isolated NO lines in balloonborne infrared solar spectra., Geophys. Res. Lett., 7, 673&amp;ndash;676, 1980. </reference>
		<reference numeration="26" content_type="text"> Orsolini, Y.: Long-lived tracer patterns in the summer polar stratosphere, Geophys. Res. Lett., 28, 3855&amp;ndash;3858, 2001. </reference>
		<reference numeration="27" content_type="text"> Orsolini, Y. and Nikulin, G.: A low-ozone episode during the European heatwave of August 2003, Q. J. Roy. Meteor. Soc., 132, 667&amp;ndash;680, 2006. </reference>
		<reference numeration="28" content_type="text"> Ross, D. E. M., Pyle, J. A., Harris, N. R. P., McIntyre, J. D., Millard, G. A., Robinson, A. D., and Busen, R.: Investigation of Arctic ozone depletion sampled over midlatitudes during the Egrett Campaign of spring/summer 2000, Atmos. Chem. Phys., 4, 141&amp;ndash;168, 2004. </reference>
		<reference numeration="29" content_type="text"> Rothman, L. S., Rinsland, C. P., Goldman, A., Massie, S. T., Edwards, D. P., Flaud, J.-M., Perrin, A., Camy-Peyret, C., Dana, V., Mandin, J.-Y., Chroeder, J., McCann, A., Gamache, R. R., Wattson, R. B., Yoshino, K., Chance, K. V., Jucks, W., Brown, L. R., Nemtchinov, V., and Varanasi, P.: The HITRAN molecular spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 edition, J. Quant. Spectrosc. Radiat. Transfer, 60, 665&amp;ndash;710, 1998. </reference>
		<reference numeration="30" content_type="text"> Sankey, D. and Shepherd, T. G.: Correlation of long-lived chemical species in a middle atmosphere general circulation model, J. Geophys. Res, 108(D16), 4494, doi:10.1029/2002JD002799, 2003. </reference>
		<reference numeration="31" content_type="text"> Shepherd, T. G.: Transport in the middle atmosphere, J. Meteorol. Soc. Japan, in press, 2007. </reference>
		<reference numeration="32" content_type="text"> Solomon, S., Portmann, R. W., Garcia, R. R., Randel, W., Wu, F., Nagatani, R., Gleason, J., Thomason, L. W., Poole, L. R., and McCormick, M. P.: Ozone depletion at midlatitudes: coupling of volcanic aerosols and temperatute variability to anthropogenic chlorine., Geophys. Res. Lett., 25, 1871&amp;ndash;1874, 1998. </reference>
		<reference numeration="33" content_type="text"> Strong, K., Bailak, G., Barton, D., Bassford, M. R., Blatheiwick, R. D., Brown, S., Chartrand, D., Davies, J., Drummond, J. R., Fogal, P. F., Forsberg, E., Hall, R., Jofre, A., Kaminski, J., Kosters, J., Laurin, C., McConnell, J. C., McElroy, C. T., McLinden, C. A., Melo, S. M. L., Menzies, K., Midwinter, C., Murcray, F. J., Nowlan, C., Olson, R. J., Quine, B. M., Rochon, Y., Savastiouk, V., Solheim, B., Sommerfeldt, D., Ullberg, A., Werchohlad, S., Wu, H., and Wunch, D.: MANTRA &amp;ndash; a balloon mission to study the odd-nitrogen budget of the stratosphere., Atmos. Ocean, 43(4), 283&amp;ndash;299, 2005. </reference>
		<reference numeration="34" content_type="text"> Tarasick, D. W., Fioletov, V. E., Wardle, D. I., Kerr, J. B., and Davies, J.: Changes in the vertical distribution of ozone over Canada from ozonesondes: 1980&amp;ndash;2001, J. Geophys. Res., 110, D02307, doi:10.1029/2004JD009693, 2005. </reference>
		<reference numeration="35" content_type="text"> Tegtmeier, S. and Shepherd, T. G.: Persistence and photochemical dacay of springtime total ozone anolamies in the Canadian Middle Atmosphere Model, Atmos. Chem. Phys., 7, 485&amp;ndash;493, 2007. </reference>
		<reference numeration="36" content_type="text"> WMO 2006: Ozone Assessment, IPCC Special Report on Safeguarding the Ozone Layer, 2005. </reference>
		<reference numeration="37" content_type="text"> Wunch, D., Tingley, M. P., Shepherd, T. G., Drummond, J. R., Moore, G. W. K., and Strong, K.: Climatology and predictability of the late summer stratospheric zonal wind turnaround over Vanscoy, Saskatchewan, Atmos.-Ocean, 43(4), 301&amp;ndash;313, 2005. </reference>
	</references>
</article>

