Atmos. Chem. Phys. Discuss., 6, 9583-9602, 2006
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Mirror image hydrocarbons from Tropical and Boreal forests
J. Williams, N. Yassaa, S. Bartenbach, and J. Lelieveld
Air Chemistry Department, Max-Planck Institute for Chemistry, J. J. Becher Weg 27, 55020 Mainz, Germany

Abstract. Monoterpenes, emitted in large quantities by trees to attract pollinators and repel herbivores, can exist in mirror image forms called enantiomers. In this study such enantiomeric pairs have been measured in ambient air over extensive forest ecosystems in South America and northern Europe. For the dominant monoterpene, α-pinene, the (–)-form was measured in large excess over the (+)-form over the Tropical rainforest, whereas the reverse was observed over the Boreal forest. Interestingly, over the Tropical forest (–)-α-pinene did not correlate with its own enantiomer, but correlated well with isoprene. The results indicate a remarkable ecosystem scale enantiomeric fingerprint and a nexus between the biosphere and atmosphere.

Citation: Williams, J., Yassaa, N., Bartenbach, S., and Lelieveld, J.: Mirror image hydrocarbons from Tropical and Boreal forests, Atmos. Chem. Phys. Discuss., 6, 9583-9602, doi:10.5194/acpd-6-9583-2006, 2006.
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