Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 6 5 2006 10.5194/acpd-6-8917-2006 http://www.atmos-chem-phys-discuss.net/6/8917/2006/ http://www.atmos-chem-phys-discuss.net/6/8917/2006/acpd-6-8917-2006.html http://www.atmos-chem-phys-discuss.net/6/8917/2006/acpd-6-8917-2006.pdf 8917 8960 2006-09-25 Characterization of the ²²²Rn family turbulent transport in the convective atmospheric boundary layer J.-F. Vinuesa S. Galmarini European Commission – DG Joint Research Centre, Institute for Environment and Sustainability, Italy The combined effect of turbulent transport and radioactive decay on the distribution of ²²²Rn and its progeny in convective atmospheric boundary layers (CBL) is investigated. Large eddy simulation is used to simulate their dispersion in steady state CBL and in unsteady conditions represented by the growth of a CBL within a pre-existing reservoir layer. <br><br> The exact decomposition of the concentration and flux budget equations under steady state conditions allowed us to determine which processes are responsible for the vertical distribution of ²²²Rn and its progeny. Their mean concentrations are directly correlated with their half-life, e.g.&nbsp;²²²Rn and ²¹⁰Pb are the most abundant whereas ²¹⁸Po show the lowest concentrations. ²²²Rn flux decreases linearly with height and its flux budget is similar to the one of inert emitted scalar, i.e., a balance between on the one hand the gradient and the buoyancy production terms, and on the other hand the pressure and dissipation at smaller scales which tends to destroy the fluxes. While ²²²Rn exhibits the typical bottom-up behavior, the maximum flux location of the daughters is moving upwards while their rank in the ²²²Rn progeny is increasing leading to a typical top-down behavior for ²¹⁰Pb. We also found that ²²²Rn short-lived daughters, e.g.&nbsp;²¹⁸Po and ²¹⁴Pb, have relevant radioactive decaying contributions acting as flux sources leading to deviations from the linear flux shape. In addition, while analyzing the vertical distribution of the radioactive decay contributions to the concentrations, e.g.&nbsp;the decaying zone, we found a discrepancy in height of ²²²Rn daughters' radioactive transformations. <br><br> Under unsteady conditions, the same behaviors reported under steady state conditions are found: deviation of the fluxes from the linear shape for ²¹⁸Po, enhanced discrepancy in height of the radioactive transformation contributions for all the daughters. In addition, ²²²Rn and its progeny concentrations collapse due to the rapid growth of the CBL. The analysis emphasizes the crucial role of turbulent transport in the behavior of ²²²Rn morning concentrations, in particular the ventilation at the top of the boundary layer that leads to the dilution of ²²²Rn by mixing with radon low concentration air.