Atmos. Chem. Phys. Discuss., 6, 11877-11912, 2006
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Scavenging of black carbon in mixed phase clouds at the high alpine site Jungfraujoch
J. Cozic1, B. Verheggen1,5, S. Mertes2, P. Connolly3, K. Bower3, A. Petzold4, U. Baltensperger1, and E. Weingartner1
1Laboratory for Atmospheric Chemistry, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
2Leibniz-Institute for Tropospheric Research, 04318 Leipzig, Germany
3School of Earth, Atmospheric and Environmental Sciences, University of Manchester, M60 1QD, UK
4Institute for Atmospheric Physics, German Aerospace Centre, 82234 Wessling, Germany
5now at: Institute for Atmospheric and Climate Sciences, ETH Zürich, 8092, Switzerland

Abstract. The scavenging of black carbon (BC) in liquid and mixed phase clouds was investigated during intensive experiments in winter 2004, summer 2004 and winter 2005 at the high alpine research station Jungfraujoch (3580 m a.s.l., Switzerland). Aerosol residuals were sampled behind two well characterized inlets; a total inlet which collected cloud particles (drops and ice particles) as well as interstitial aerosol particles; an interstitial inlet which collected only interstitial (unactivated) aerosol particles. BC concentrations were measured behind each of these inlets along with the submicrometer aerosol number size distribution, from which a volume concentration was derived. These measurements were complemented by in-situ measurements of cloud microphysical parameters. BC was found to be scavenged into the cloud phase to the same extent as the bulk aerosol, which suggests that BC was covered with soluble material through aging processes, rendering it more hygroscopic. The scavenged fraction of BC (FScav,BC), defined as the fraction of BC that is incorporated into cloud droplets and ice crystals, decreases with increasing cloud ice mass fraction (IMF) from FScav,BC=60% in liquid phase clouds to FScav,BC~10% in mixed-phase clouds with IMF>0.2. This is explained by the evaporation of liquid droplets in the presence of ice crystals (Wegener-Bergeron-Findeisen process), releasing BC containing cloud condensation nuclei back into the interstitial phase. In liquid clouds, the scavenged BC fraction is found to decrease with decreasing cloud liquid water content. The scavenged BC fraction is also found to decrease with increasing BC mass concentration since there is an increased competition for the available water vapour.

Citation: Cozic, J., Verheggen, B., Mertes, S., Connolly, P., Bower, K., Petzold, A., Baltensperger, U., and Weingartner, E.: Scavenging of black carbon in mixed phase clouds at the high alpine site Jungfraujoch, Atmos. Chem. Phys. Discuss., 6, 11877-11912, doi:10.5194/acpd-6-11877-2006, 2006.
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