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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-6-10567-2006</article-id>
<title-group>
<article-title>Boundary layer concentrations and landscape scale emissions of volatile organic compounds in early spring</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Haapanala</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rinne</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hakola</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hellén</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Laakso</surname>
<given-names>L.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lihavainen</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Janson</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kulmala</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>University of Helsinki, Department of Physical Sciences, Helsinki, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Finnish Meteorological Institute, Air Chemistry Laboratory, Helsinki, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Finnish Meteorological Institute, Climate and Global Change Research, Helsinki, Finland</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Stockholm University, Department of Applied Environmental Science, Stockholm, Sweden</addr-line>
</aff>
<pub-date pub-type="epub">
<day>18</day>
<month>10</month>
<year>2006</year>
</pub-date>
<volume>6</volume>
<issue>5</issue>
<fpage>10567</fpage>
<lpage>10589</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/6/10567/2006/acpd-6-10567-2006.html">This article is available from http://www.atmos-chem-phys-discuss.net/6/10567/2006/acpd-6-10567-2006.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/6/10567/2006/acpd-6-10567-2006.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/6/10567/2006/acpd-6-10567-2006.pdf</self-uri>
<abstract>
<p>Boundary layer concenrations of several volatile organic compounds (VOC)
were measured during two campaigns in springs of 2003 and 2006. Measurements
were conducted over boreal forests near SMEAR II measurement station in
Hyyti&amp;#228;l&amp;#228;, Southern Finland. In 2003 the measuremens were performed
using light aircraft and in 2006 using hot air ballon. Isoprene
concentrarions were low, usually below detection limit. This is explained by
low biogenic production due to cold weather. Monoterpenes were observed
frequently. Average total monoterpene concentration in the boundary layer
was 33 ppt&lt;sub&gt;v&lt;/sub&gt;. Many anthropogenic compounds e.g.&amp;nbsp;benzene, xylene and
toluene, were observed in high amounts. Ecosystem scale surface emissions
were estimated using simple mixed box budget methodology. Total monoterpene
fluxes varied up to 80 &amp;mu;g m&lt;sup&gt;&amp;minus;2&lt;/sup&gt; h&lt;sup&gt;&amp;minus;1&lt;/sup&gt;, &amp;alpha;-pinene
contributing typically more than two thirds of that. Highest fluxes of
anthropogenic compounds were those of p/m xylene.</p>
</abstract>
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