<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-5-9907-2005</article-id>
<title-group>
<article-title>Modeling the possible role of iodine oxides in atmospheric new particle formation</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pechtl</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lovejoy</surname>
<given-names>E. R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Burkholder</surname>
<given-names>J. B.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>von Glasow</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute for Environmental Physics, University of Heidelberg, Heidelberg, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Aeronomy Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>13</day>
<month>10</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>5</issue>
<fpage>9907</fpage>
<lpage>9952</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/5/9907/2005/acpd-5-9907-2005.html">This article is available from http://www.atmos-chem-phys-discuss.net/5/9907/2005/acpd-5-9907-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/5/9907/2005/acpd-5-9907-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/5/9907/2005/acpd-5-9907-2005.pdf</self-uri>
<abstract>
<p>We studied the possible role of iodine oxides in atmospheric new particle
formation with the one-dimensional marine boundary layer model MISTRA,
which includes chemistry in the gas and aerosol phase as well as aerosol
microphysics. The chemical reaction set focuses on halogen
(Cl-Br-I) chemistry. We included a two-step nucleation parameterization, where
in the first step, the &apos;&apos;real&apos;&apos; nucleation process is parameterized,
i.e., the formation of cluster-sized nuclei via homogeneous condensation of gases.
We considered both ternary sulfuric acid-ammonia-water nucleation and
homomolecular homogeneous OIO nucleation.
For the latter, we derived a parameterization based
on combined laboratory-model studies. The second step of the nucleation
parameterization treats the &apos;&apos;apparent&apos;&apos; nucleation rate, i.e., the growth
of clusters into the model&apos;s lowest size bin by condensable vapors such as OIO.
We compared different scenarios for a clean marine versus a polluted continental
background atmosphere. In every scenario, we assumed the air to move,
independent of its origin, first over a coastal region (where it is exposed
to surface fluxes of different reactive iodine precursors) and later over the open ocean.
According to these sensitivity studies, in the clean marine background atmosphere
OIO can be responsible for both
homogeneous nuclei formation and the subsequent growth of the clusters
to detectable sizes. In contrast to this, in the continental case with its higher
levels of pollutants, gas phase OIO mixing ratios, and hence related nucleation rates,
are significantly lower. Compared to ternary H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;-NH&lt;sub&gt;3&lt;/sub&gt;-H&lt;sub&gt;2&lt;/sub&gt;O
nucleation, homogeneous OIO nucleation can be neglected
for new particle formation in this case, but OIO can contribute to
early particle growth, i.e., to apparent nucleation rates.
In general, we found OIO to be more important for the growth of newly formed
particles than for the formation of new nuclei itself.
According to our studies, observations of particle &apos;&apos;bursts&apos;&apos; can only
be explained by hot spot-like, not by homogeneously distributed emissions.</p>
</abstract>
<counts><page-count count="46"/></counts>
</article-meta>
</front>
<body/>
<back>
</back>
</article>