Atmos. Chem. Phys. Discuss., 5, 8149-8207, 2005
www.atmos-chem-phys-discuss.net/5/8149/2005/
doi:10.5194/acpd-5-8149-2005
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Size distribution and hygroscopic properties of aerosol particles from dry-season biomass burning in Amazonia
J. Rissler1, A. Vestin1, E. Swietlicki1, G. Fisch2, J. Zhou1, P. Artaxo3, and M. O. Andreae4
1Div. of Nuclear Physics, Lund University, P.O. Box 118, SE-221 00 Lund, Sweden
2Centro Técnico Aeroespacial (CTA/IAE), Praça Marechal Eduardo Gomes, 50, 12228-904, São José dos Campos, Brazil
3Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo, Brazil
4Max Planck Institute for Chemistry, P.O. Box 3060, 55020 Mainz, Germany

Abstract. Aerosol particle number size distributions and hygroscopic properties were measured at a pasture site in the southwestern Amazon region (Rondonia). The measurements were performed 11 September–14 November 2002 as part of LBA-SMOCC (Large scale Biosphere atmosphere experiment in Amazonia – SMOke aerosols, Clouds, rainfall and Climate), and cover the later part of the dry season (with heavy biomass burning), a transition period, and the onset of the wet period.

Particle number size distributions were measured with a DMPS (Differential Mobility Particle Sizer, 3–850 nm) and an APS (Aerodynamic Particle Sizer), extending the distributions up to 3.3 µm in diameter. An H-TDMA (Hygroscopic Tandem Differential Mobility Analyzer) measured the hygroscopic diameter growth factors (Gf) at 90% relative humidity (RH), for particles with dry diameters (dp) between 20–440 nm, and at several occasions RH scans (30–90% RH) were performed for 165 nm particles. These data provide the most extensive characterization of Amazonian biomass burning aerosol, with respect to particle number size distributions and hygroscopic properties, presented until now. The evolution of the convective boundary layer over the course of the day causes a distinct diel variation in the aerosol physical properties, which was used to get information about the properties of the aerosol at higher altitudes.

The number size distributions averaged over the three time periods showed three modes; a nucleation mode with count median diameters (CMD) of ~12 nm, an Aitken mode (CMD = 61–92 nm) and an accumulation mode (CMD = 128–190 nm). The two larger modes were shifted towards larger CMD with increasing influence from biomass burning.
RH revealed a somewhat external mixture with two groups of particles; here denoted nearly hydrophobic (Gf~1.09 for 100 nm particles) and moderately hygroscopic (Gf~1.26). While the hygroscopic growth factors were surprisingly similar over the defined periods, the number fraction of particles belonging to each hygroscopic group varied more, with the dry period aerosol being more dominated by nearly hydrophobic particles. As a result the total particle water uptake rose going into the cleaner period.

The fraction of moderately hygroscopic particles was consistently larger for particles in the accumulation mode compared to the Aitken mode for all periods. Scanning the H-TDMA over RH (30–90% RH) showed no deliquescence behavior. A parameterization of both Gf (RH) and Gf(dp), is given.


Citation: Rissler, J., Vestin, A., Swietlicki, E., Fisch, G., Zhou, J., Artaxo, P., and Andreae, M. O.: Size distribution and hygroscopic properties of aerosol particles from dry-season biomass burning in Amazonia, Atmos. Chem. Phys. Discuss., 5, 8149-8207, doi:10.5194/acpd-5-8149-2005, 2005.
 
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