Atmos. Chem. Phys. Discuss., 5, 573-605, 2005
www.atmos-chem-phys-discuss.net/5/573/2005/
doi:10.5194/acpd-5-573-2005
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
The contribution of sulphuric acid to atmospheric particle formation and growth: a comparison between boundary layers in Northern and Central Europe
V. Fiedler1,2, M. Dal Maso2, M. Boy2, H. Aufmhoff1, J. Hoffmann1, T. Schuck1, W. Birmili3, F. Arnold1, and M. Kulmala2
1Max-Planck Institute for Nuclear Physics, (MPIK), Atmospheric Physics Division, P.O. Box 103980, D-69029 Heidelberg, Germany
2University of Helsinki, Dept. Physical Sciences, P.O. Box 64, FIN-00014 Univ. of Helsinki, Finland
3Leibniz Institute for Tropospheric Research, Permoserstr. 15, D-04318 Leipzig, Germany

Abstract. Atmospheric gaseous sulphuric acid was measured and its influence on particle formation and growth was investigated building on aerosol data. The measurements were part of the EU-project QUEST and took place at two different measurement sites in Northern and Central Europe (Hyytiälä, Finland, March–April 2003 and Heidelberg, Germany, March–April 2004). From a comprehensive data set including particle number size distributions, sulphuric acid, and meteorological data, particle growth rates, particle formation rates and source rates of condensable vapors were calculated. Growth rates were determined in two different ways, from particle size distributions as well as from a so-called timeshift analysis. Moreover, correlations between sulphuric acid and particle number concentration between 3 and 6 nm were examined and the influence of different air masses was analyzed. Measured concentrations of sulphuric acid were in the range from 2·106 to 16·106 cm-3. The gaseous sulphuric acid lifetime with respect to condensation on aerosol particles ranged from 2 to 33 min in Hyytiälä and from 28 s to 8 min in Heidelberg. Most calculated values (growth rates, formation rates, vapor source rates) were considerably higher in Central Europe (Heidelberg), due to the more polluted air and higher preexistent aerosol concentrations. Close correlations between H2SO4 and nucleation mode particles (size range: 3–6 nm) were found on many days at both sites but several observation days also lacked such correlations. The percentage contribution of sulphuric acid to particle growth was below 10% at both places, to initial growth below 20%. An air mass analysis indicated that at Heidelberg new particles were formed predominantly in air advected from southwesterly directions.

Citation: Fiedler, V., Dal Maso, M., Boy, M., Aufmhoff, H., Hoffmann, J., Schuck, T., Birmili, W., Arnold, F., and Kulmala, M.: The contribution of sulphuric acid to atmospheric particle formation and growth: a comparison between boundary layers in Northern and Central Europe, Atmos. Chem. Phys. Discuss., 5, 573-605, doi:10.5194/acpd-5-573-2005, 2005.
 
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