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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-5-11861-2005</article-id>
<title-group>
<article-title>Atmospheric transport and deposition of Indonesian volcanic emissions</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pfeffer</surname>
<given-names>M. A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Langmann</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Graf</surname>
<given-names>H.-F.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of the Atmosphere in the Earth System, Max-Planck-Institute for Meteorology, Hamburg, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Geography, University of Cambridge, Cambridge, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>21</day>
<month>11</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>6</issue>
<fpage>11861</fpage>
<lpage>11897</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/5/11861/2005/acpd-5-11861-2005.html">This article is available from http://www.atmos-chem-phys-discuss.net/5/11861/2005/acpd-5-11861-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/5/11861/2005/acpd-5-11861-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/5/11861/2005/acpd-5-11861-2005.pdf</self-uri>
<abstract>
<p>A regional climate model study has been performed to investigate the transport
and atmospheric loss rates of emissions from Indonesian volcanoes and the
sensitivity of these emissions to meteorological conditions and the solubility of the
released emissions.  Two experiments were conducted: 1) volcanic sulfur released
as primarily SO&lt;sub&gt;2&lt;/sub&gt; and oxidation to SO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;2&amp;minus;&lt;/sup&gt; determined
by considering the major tropospheric chemical reactions; and 2) PbCl&lt;sub&gt;2&lt;/sub&gt;
released as an infinitely soluble passive tracer.  The first experiment was used to
calculate SO&lt;sub&gt;2&lt;/sub&gt; loss rates from each active volcano resulting in an annual mean
loss rate for all volcanoes of 1.1&amp;times;10&lt;sup&gt;&amp;minus;5&lt;/sup&gt;&amp;nbsp;s&lt;sup&gt;&amp;minus;1&lt;/sup&gt;, or an e-folding
rate of approximately 1 day.  SO&lt;sub&gt;2&lt;/sub&gt; loss rate was found to vary seasonally, be poorly
correlated with wind speed, and uncorrelated with temperature or relative humidity.  The
variability of SO&lt;sub&gt;2&lt;/sub&gt; loss rates is found to be correlated with the variability of wind
speeds, suggesting that it is much more difficult to establish a &apos;&apos;typical&apos;&apos; SO&lt;sub&gt;2&lt;/sub&gt; loss rate
for volcanoes that are exposed to inconsistent winds.  Within an average distance of 69&amp;nbsp;km
away from the active Indonesian volcanoes,
53% of SO&lt;sub&gt;2&lt;/sub&gt; is lost due to conversion to SO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;2&amp;minus;&lt;/sup&gt;, 42%
due to dry deposition, and 5% is lost due to lateral transport away from the dominant
direction of plume travel.  The solubility of volcanic emissions in water is shown to
have a major influence on their atmospheric transport and deposition.   High
concentrations of PbCl&lt;sub&gt;2&lt;/sub&gt; are predicted to be deposited near to
the volcanoes while volcanic S travels further away until removal from
the atmosphere primarily via the wet deposition of H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;.  The
ratio of the concentration of PbCl&lt;sub&gt;2&lt;/sub&gt; to SO&lt;sub&gt;2&lt;/sub&gt; is found to
exponentially decay at increasing distance from the volcanoes.  The more rapid
removal of highly soluble species should be considered when making observations of
SO&lt;sub&gt;2&lt;/sub&gt; in an aged plume and relating this concentration to other
volcanic species.  An assumption that the ratio between the concentrations of highly soluble
volcanic compounds and S within an aged plume is equal to that observed in
fumarolic gases will result in an overestimation of the atmospheric concentration of highly
soluble species.</p>
</abstract>
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