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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-5-11215-2005</article-id>
<title-group>
<article-title>The overwhelming role of soils in the global atmospheric hydrogen cycle</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rhee</surname>
<given-names>T. S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Brenninkmeijer</surname>
<given-names>C. A. M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Röckmann</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Max Planck Institute for Chemistry, Atmospheric Chemistry Division, Mainz, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Max Planck Institute for Nuclear Physics, Atmospheric Physics Division, Heidelberg, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>now at: Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands</addr-line>
</aff>
<pub-date pub-type="epub">
<day>02</day>
<month>11</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>6</issue>
<fpage>11215</fpage>
<lpage>11248</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/5/11215/2005/acpd-5-11215-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/5/11215/2005/acpd-5-11215-2005.pdf</self-uri>
<abstract>
<p>The removal of molecular hydrogen (H&lt;sub&gt;2&lt;/sub&gt;) from the atmosphere is dominated
by the uptake in soils. Notwithstanding, estimates of the magnitude of this
important process on a global scale are highly uncertain. The CARIBIC
aircraft observations of the seasonal variations of H&lt;sub&gt;2&lt;/sub&gt; and its D/H
isotopic ratio in the northern hemisphere allow an independent, better
constrained estimate. We derive that 82% of the annual turnover of
tropospheric H&lt;sub&gt;2&lt;/sub&gt; is due to soil uptake, equaling 88 (&amp;plusmn;11) Tg a&lt;sup&gt;&amp;minus;1&lt;/sup&gt;,
of which the northern hemisphere alone accounts for 62 (&amp;plusmn;10) Tg a&lt;sup&gt;&amp;minus;1&lt;/sup&gt;.
Our calculations further show that tropospheric H&lt;sub&gt;2&lt;/sub&gt;
has a lifetime of only 1.4 (&amp;plusmn;0.2) years &amp;ndash; significantly shorter than
the recent estimate of ~2 years &amp;ndash; which is expected to decrease in the
future. In addition, our independent top-down approach, confined by the
global and hemispheric sinks of H&lt;sub&gt;2&lt;/sub&gt;, indicates 64 (&amp;plusmn;12) Tg a&lt;sup&gt;&amp;minus;1&lt;/sup&gt;
emissions from various sources of volatile organic compounds by
photochemical oxidation in the atmosphere. This estimate is as much as up to
60% larger than the previous estimates. This large airborne production
of H&lt;sub&gt;2&lt;/sub&gt; helps to explain the fairly homogeneous distribution of H&lt;sub&gt;2&lt;/sub&gt;
in the troposphere.</p>
</abstract>
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