Atmos. Chem. Phys. Discuss., 4, 8579-8607, 2004
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Nitric acid trihydrate (NAT) formation at low NAT supersaturations
C. Voigt1, H. Schlager1, B. P. Luo2, A. Dörnbrack1, A. Roiger1, P. Stock1, J. Curtius3, H. Vössing3, S. Borrmann3,4, S. Davies5, P. Konopka6, C. Schiller6, G. Shur7, and T. Peter2
1Institut für Physik der Atmosphäre (IPA), DLR Oberpfaffenhofen, D-82234 Wessling, Germany
2Institut für Atmosphäre und Klima, ETH Zürich, Hönggerberg HPP, CH-8093 Zürich, Switzerland
3Institut für Physik der Atmosphäre, Universität Mainz, D-55099 Mainz, Germany
4Max-Planck-Institut für Chemie, D-55128 Mainz, Germany
5School of Environment, University of Leeds LS9JT, UK
6Forschungszentrum Jülich, ICG-I, D-52425 Jülich, Germany
7Central aerological observatory, Moscow, reg. 141700, Russia

Abstract. A polar stratospheric cloud (PSC) was observed on 6 February 2003 in the Arctic stratosphere by in-situ measurements onboard the high-altitude research aircraft Geophysica. Low number densities (~10−4 cm−3) of nitric acid (HNO3) containing particles – probably NAT – with diameters up to 6 µm were measured at altitudes between 18 and 20 km. These particles have the potential to grow further and to remove HNO3 from the stratosphere, thereby enhancing polar ozone loss. Interestingly, the NAT particles formed in less than a day at temperatures T>TNAT−3.5 K, just slightly below the NAT equilibrium temperature TNAT. This unique measurement of PSC formation at extremely low NAT saturation ratios (SNAT≤11) constrains current NAT nucleation theories. In particular, NAT formation on ice can for certain be excluded. Conversely, we suggest that meteoritic particles may be favorable candidates for triggering nucleation of NAT at the observed low number densities.

Citation: Voigt, C., Schlager, H., Luo, B. P., Dörnbrack, A., Roiger, A., Stock, P., Curtius, J., Vössing, H., Borrmann, S., Davies, S., Konopka, P., Schiller, C., Shur, G., and Peter, T.: Nitric acid trihydrate (NAT) formation at low NAT supersaturations, Atmos. Chem. Phys. Discuss., 4, 8579-8607, doi:10.5194/acpd-4-8579-2004, 2004.
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