Atmospheric Chemistry and Physics Discussions www.atmos-chem-phys-discuss.net 1680-7367 1680-7375 4 5 2004 10.5194/acpd-4-5733-2004 http://www.atmos-chem-phys-discuss.net/4/5733/2004/ http://www.atmos-chem-phys-discuss.net/4/5733/2004/acpd-4-5733-2004.html http://www.atmos-chem-phys-discuss.net/4/5733/2004/acpd-4-5733-2004.pdf 5733 5788 2004-09-24 Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons C. Bloss c.bloss@chemistry.leeds.ac.uk V. Wagner M. E. Jenkin R. Volkamer W. J. Bloss J. D. Lee D. E. Heard K. Wirtz M. Martin-Reviejo G. Rea J. C. Wenger M. J. Pilling School of Chemistry, University of Leeds, Leeds LS2 9JT, UK Imperial College London, Silwood Park, Ascot, Berkshire SL5 7PY, UK Institut für Umweltphysik, University of Heidelberg, INF 229, 69120 Heidelberg, Germany Centro de Estudios Ambientales del Mediterraneo, C. Charles R. Darwin 14, 46980 Paterna, Spain Department of Chemistry, National University of Ireland, University College Cork, Cork, Ireland now at: Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA now at: Department of Chemistry, University of York, York, YO10 5DD, UK The Master Chemical Mechanism has been updated from MCMv3 to MCMv3.1 in order to take into account recent improvements in the understanding of aromatic photo-oxidation. Newly available kinetic and product data from the literature has been incorporated into the mechanism. In particular, the degradation mechanisms for hydroxyarenes have been revised following the observation of high yields of ring-retained products, and product studies of aromatic oxidation under relatively low NO_x conditions have provided new information on the branching ratios to first generation products. Experiments have been carried out at the European Photoreactor (EUPHORE) to investigate key subsets of the toluene system. These results have been used to test our understanding of toluene oxidation, and where possible, refine the degradation mechanisms. The evaluation of MCMv3 and MCMv3.1 using data on benzene, toluene, <i>p</i>-xylene and 1,3,5-trimethylbenzene photosmog systems is described in a companion paper, and significant model shortcomings are identified. Ideas for additional modifications to the mechanisms, and for future experiments to further our knowledge of the details of aromatic photo-oxidation are discussed.