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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-5433-2004</article-id>
<title-group>
<article-title>Initial steps of aerosol growth</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kulmala</surname>
<given-names>O.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Laakso</surname>
<given-names>L.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lehtinen</surname>
<given-names>K. E. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Riipinen</surname>
<given-names>I.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dal Maso</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Anttila</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kerminen</surname>
<given-names>V.-M.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hõrrak</surname>
<given-names>U.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vana</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tammet</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Physical Sciences, Division of Atmospheric Sciences, P.O. Box 64, FIN-00014 University of Helsinki, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Finnish Meteorological Institute, Air Quality Research, Sahaajankatu 22E, FIN-00880 Helsinki, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institute of Environmental Physics, University of Tartu, Ülikooli 18, 50090 Tartu, Estonia</addr-line>
</aff>
<pub-date pub-type="epub">
<day>17</day>
<month>09</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>5</issue>
<fpage>5433</fpage>
<lpage>5454</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>The formation and growth of atmospheric aerosols depend on several steps,
namely nucleation, initial steps of growth and subsequent &amp;ndash; mainly
condensational &amp;ndash; growth. This work focuses on the initial steps of growth,
meaning the growth right after nucleation, where the interplay of curvature
effects and thermodynamics has a significant role on the growth kinetics.
More specifically, we investigate how ion clusters and aerosol particles
grow from 1.5 nm to 20 nm in atmospheric conditions using experimental data
obtained by air ion and aerosol spectrometers. The measurements have been
performed at a boreal forest site in Finland. The observed trend that the
growth rate seems to increase as a function of size can be used to
investigate possible growth mechanisms. Such a growth rate is consistent
with a recently suggested nano-K&amp;#246;hler mechanism, in which growth is
activated at a certain size with respect to condensation of organic vapors.
The results also imply that charge-enhance growth associated with
ion-mediated nucleation plays only a minor role in the initial steps of
growth, since it would imply a clear decrease of the growth rate with size.
Finally, further evidence was obtained on the earlier suggestion that
atmospheric nucleation and the subsequent growth of fresh nuclei are likely
to be uncoupled phenomena via different participating vapors.</p>
</abstract>
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