Atmos. Chem. Phys. Discuss., 4, 5045-5074, 2004
www.atmos-chem-phys-discuss.net/4/5045/2004/
doi:10.5194/acpd-4-5045-2004
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Three-dimensional model study of the arctic ozone loss in 2002/2003 and comparison with 1999/2000 and 2003/2004
W. Feng1, M. P. Chipperfield1, S. Davies1, B. Sen2, G. Toon2, J. F. Blavier2, C. R. Webster2, C. M. Volk3, A. Ulanovsky4, F. Ravegnani5, P. von der Gathen6, H. Jost7, E. C. Richard8, and H. Claude9
1Institute for Atmospheric Science, School of the Environment, University of Leeds, Leeds, UK
2NASA Jet Propulsion Laboratory, Pasadena, CA, USA
3J. W. Goethe University Frankfurt, Germany
4Central Aerological Observatory (CAO), Moscow, Russia
5Institute of Atmospheric Sciences and Climate (ISAC), Italian National Research Council, Bologna, Italy
6Alfred Wegener Institute, Potsdam, Germany
7NASA Ames, Moffett Field, CA, USA
8Aeronomy Laboratory, NOAA, Boulder, CO, USA
9Deutscher Wetterdienst, Germany

Abstract. We have used the SLIMCAT 3-D off-line chemical transport model (CTM) to quantify the Arctic chemical ozone loss in the year 2002/2003 and compare it with similar calculations for the winters 1999/2000 and 2003/2004. Recent changes to the CTM have improved the model's ability to reproduce polar chemical and dynamical processes. The updated CTM uses σ-θ as a vertical coordinate which allows it to extend down to the surface. The CTM has a detailed stratospheric chemistry scheme and now includes a simple NAT-based denitrification scheme in the stratosphere.

In the model runs presented here the model was forced by ECMWF ERA40 and operational analyses. The model used 24 levels extending from the surface to ~55 km and a horizontal resolution of either 7.5°×7.5° or 2.8°×2.8°. Two different radiation schemes, MIDRAD and the CCM scheme, were used to diagnose the vertical motion in the stratosphere. Based on tracer observations from balloons and aircraft, the more sophisticated CCM scheme gives a better representation of the vertical transport in this model which includes the troposphere. The higher resolution model generally produces larger chemical O3 depletion, which agrees better with observations.

The CTM results show that very early chemical ozone loss occurred in December 2002 due to extremely low temperatures and early chlorine activation in the lower stratosphere. Thus, chemical loss in this winter started earlier than in the other two winters studied here. In 2002/2003 the local polar ozone loss in the lower stratosphere was ~40% before the stratospheric final warming. Larger ozone loss occurred in the cold year 1999/2000 which had a persistently cold and stable vortex during most of the winter. For this winter the current model, at a resolution of 2.8°×2.8°, can reproduce the observed loss of over 70% locally. In the warm and more disturbed winter 2003/2004 the chemical O3 loss was generally much smaller, except above 620 K where large losses occurred due to a period of very low minimum temperatures at these altitudes.


Citation: Feng, W., Chipperfield, M. P., Davies, S., Sen, B., Toon, G., Blavier, J. F., Webster, C. R., Volk, C. M., Ulanovsky, A., Ravegnani, F., von der Gathen, P., Jost, H., Richard, E. C., and Claude, H.: Three-dimensional model study of the arctic ozone loss in 2002/2003 and comparison with 1999/2000 and 2003/2004, Atmos. Chem. Phys. Discuss., 4, 5045-5074, doi:10.5194/acpd-4-5045-2004, 2004.
 
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