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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-4737-2004</article-id>
<title-group>
<article-title>The origin of sea salt in snow on Arctic sea ice and in coastal regions</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Domine</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sparapani</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ianniello</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Beine</surname>
<given-names>H. J.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>CNRS, Laboratoire de Glaciologie et Geophysique de l’Environnement, BP 96, 38402 Saint Martin d’Hères cedex, France</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>C.N.R. &amp;ndash; IIA, Via Salaria Km 29,3 , I-00016 Monterotondo Scalo, Roma, Italy</addr-line>
</aff>
<pub-date pub-type="epub">
<day>24</day>
<month>08</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>4</issue>
<fpage>4737</fpage>
<lpage>4776</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/4/4737/2004/acpd-4-4737-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/4/4737/2004/acpd-4-4737-2004.pdf</self-uri>
<abstract>
<p>Snow, through its trace constituents, can have a major impact on lower
tropospheric chemistry, as evidenced by ozone depletion events (ODEs) in
oceanic polar areas. These ODEs are caused by the chemistry of bromine
compounds, that originate from sea salt bromide. According to current ideas,
bromide may be supplied to the snow surface either by upward migration from
sea ice or by frost flowers being wind-blown to the snow surface. We
investigate here the relative importance of both these processes by
analyzing mineral ions in snow samples collected near Alert and
Ny-&amp;#197;lesund (Canadian and European high Arctic) in winter and spring.
Vertical ionic profiles in the snowpack on sea ice are measured to test
upward migration of sea salt ions and to seek evidence for ion fractionation
processes. Time series of the ionic composition of surface snow layers are
investigated to quantify wind-transported ions. Upward migration of
unfractionated sea salt, to heights of at least 17 cm, was observed in snow
sampled in winter, at temperatures near &amp;minus;30&amp;deg;C, leading to Cl&lt;sup&gt;&amp;minus;&lt;/sup&gt;
concentration of several hundred &amp;micro;M. Upward migration thus has the
potential to supply ions to surface snow layers. Time series show that wind
can deposit aerosols to the top few cm of the snow, leading also to Cl&lt;sup&gt;&amp;minus;&lt;/sup&gt;
concentrations of several hundred &amp;micro;M, so that both migration from sea
ice and wind transport can significantly contribute ions to snow. At
Ny-&amp;#197;lesund, sea salt transported by wind was unfractionated, implying
that it does not come from frost flowers. In the Arctic, frost flowers thus
do not appear necessary to lead to large sea salt concentrations in surface
snow, and to supply the bromide needed for ODEs. The data obtained also
indicate that ODEs lead to significant deposition of Br&lt;sup&gt;&amp;minus;&lt;/sup&gt; to snow. We
speculate that this can also take place in coastal regions and contribute to
propagate ODEs inland. Finally, we stress the need to measure snow physical
parameters such as permeability and specific surface area, to understand
quantitatively changes in snow chemistry.</p>
</abstract>
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