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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-4019-2004</article-id>
<title-group>
<article-title>Enhanced uptake of water by oxidatively processed oleic acid</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Asad</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Mmereki</surname>
<given-names>B. T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Donaldson</surname>
<given-names>D. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Chemistry and Department of Physical and Environmental Sciences, University of Toronto, 80 St. George St., Toronto, M5S 3H6 Ont., Canada</addr-line>
</aff>
<pub-date pub-type="epub">
<day>29</day>
<month>07</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>4</issue>
<fpage>4019</fpage>
<lpage>4038</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/4/4019/2004/acpd-4-4019-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/4/4019/2004/acpd-4-4019-2004.pdf</self-uri>
<abstract>
<p>A quartz crystal microbalance apparatus has been used to measure the room
temperature uptake of water vapour by thin films of oleic acid as a function
of relative humidity, both before and following exposure of the films to
various partial pressures of gas phase ozone. A rapid increase in the
water-sorbing ability of the film is observed as its exposure to ozone is
increased, followed by a plateau region in which no additional water is
taken up. In this fully-processed region the mass of water taken up by the
film is about 4 times that of the unprocessed film. Infrared spectra of the
films, measured after variable exposures to ozone, show dramatic increases
in both the &amp;quot;free&amp;quot; and hydrogen-bonded O-H stretching regions, and a
decrease in the intensity of olefinic features. These results are consistent
with the formation of an oxygenated polymeric product or products, as well
as the gas phase products previously identified.</p>
</abstract>
<counts><page-count count="20"/></counts>
</article-meta>
</front>
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