Atmos. Chem. Phys. Discuss., 4, 3013-3043, 2004
www.atmos-chem-phys-discuss.net/4/3013/2004/
doi:10.5194/acpd-4-3013-2004
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Optical properties in the UV and visible spectral region of organic acids relevant to tropospheric aerosols
C. E. Lund Myhre and C. J. Nielsen
Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0372 Oslo, Norway

Abstract. Refractive and absorption indices in the UV and visible region of selected aqueous organic acids relevant to tropospheric aerosols are reported. The acids investigated are the aliphatic dicarboxylic acids oxalic, malonic, tartronic, succinic and glutaric acid. In addition we report data for pyruvic, pinonic, benzoic and phthalic acid. To cover a wide range of conditions we have investigated the aqueous organic acids at different concentrations spanning from highly diluted samples to concentrations close to saturation. The density of the investigated samples is reported and a parameterisation of the absorption and refractive index that allows the calculation of the optical constants of mixed aqueous organic acids at different concentrations is presented. The single scattering albedo is calculated for two size distributions using measured and a synthetic set of optical constants. The results show that tropospheric aerosols consisting of only these organic acids and water have a pure scattering effect.

Citation: Lund Myhre, C. E. and Nielsen, C. J.: Optical properties in the UV and visible spectral region of organic acids relevant to tropospheric aerosols, Atmos. Chem. Phys. Discuss., 4, 3013-3043, doi:10.5194/acpd-4-3013-2004, 2004.
 
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