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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-2991-2004</article-id>
<title-group>
<article-title>Carbonyl compounds in boreal coniferous forest air in Hyytiälä, Southern Finland</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hellén</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hakola</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Reissell</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ruuskanen</surname>
<given-names>T. M.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Finnish Meteorological Institute, Sahaajankatu 20 E, 00880 Helsinki, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>University of Helsinki, Department of Physical Sciences, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>University of Helsinki, Department of Chemistry, Finland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>03</day>
<month>06</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>3</issue>
<fpage>2991</fpage>
<lpage>3011</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/4/2991/2004/acpd-4-2991-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/4/2991/2004/acpd-4-2991-2004.pdf</self-uri>
<abstract>
<p>A variety of C&lt;sub&gt;1&lt;/sub&gt;-C&lt;sub&gt;12&lt;/sub&gt; carbonyl compounds were measured in the air of
a boreal coniferous forest located in Hyyti&amp;#228;l&amp;#228;, Southern Finland.
24-h samples were collected during March and April in 2003 using DNPH
(2,4-dinitrophenyl hydrazine) coated C&lt;sub&gt;18&lt;/sub&gt;-cartridges and analyzed by
liquid chromatography-mass spectrometry (LC-MS).

&lt;br&gt;&lt;br&gt;
Altogether 22 carbonyl compounds were quantified. The most abundant
carbonyls were acetone (24-h average 1340 ng/m&lt;sup&gt;3&lt;/sup&gt;), formaldehyde
(480 ng/m&lt;sup&gt;3&lt;/sup&gt;) and acetaldehyde (360 ng/m&lt;sup&gt;3&lt;/sup&gt;). In contrast, scaling of
concentrations against reactivity with the hydroxyl (OH) radical
significantly increased the contribution of larger aldehydes and ketones
(e.g. decanal, octanal and 6-methyl-5-hepten-2-one). Concentrations of
monoterpene reaction products nopinone (9 ng/m&lt;sup&gt;3&lt;/sup&gt;) and limona ketone
(5 ng/m&lt;sup&gt;3&lt;/sup&gt;) were low compared to the most abundant low molecular weight
carbonyls. The total concentration of carbonyl compounds in Hyyti&amp;#228;l&amp;#228;
in April/March 2003 was much higher than the concentration of aromatic
hydrocarbons and monoterpenes in April 2002.

&lt;br&gt;&lt;br&gt;
Lifetimes of the measured carbonyls with respect to reactions with OH
radicals, ozone (O&lt;sub&gt;3&lt;/sub&gt;), and nitrate (NO&lt;sub&gt;3&lt;/sub&gt;) radicals as well as
photolysis were estimated. The main sinks for most of the carbonyl compounds
in Hyyti&amp;#228;l&amp;#228; in springtime are expected to be reactions with the OH
radical and photolysis. For 6-methyl-5-hepten-2-one and limona ketone also
reactions with ozone are important. The sources of carbonyl compounds are
presently highly uncertain. Due to the relatively short lifetimes of
aldehydes and ketones, secondary biogenic and anthropogenic sources, that is
oxidation of volatile organic compounds, and primary biogenic sources are
expected to dominate in Hyyti&amp;#228;l&amp;#228;.</p>
</abstract>
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