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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-2805-2004</article-id>
<title-group>
<article-title>Global carbon monoxide as retrieved from SCIAMACHY by WFM-DOAS</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Buchwitz</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>de Beek</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bramstedt</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Noël</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bovensmann</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Burrows</surname>
<given-names>J. P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute of Environmental Physics (iup), University of Bremen FB1, Bremen, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>19</day>
<month>05</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>3</issue>
<fpage>2805</fpage>
<lpage>2837</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/4/2805/2004/acpd-4-2805-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/4/2805/2004/acpd-4-2805-2004.pdf</self-uri>
<abstract>
<p>Vertical columns of CO have been retrieved from SCIAMACHY/ENVISAT
short wave/near infrared (~2.3&amp;micro;m)
nadir spectra using the
Weighting Function Modified (WFM) DOAS retrieval algorithm.
WFM-DOAS has been applied to
a small spectral fitting window
located in SCIAMACHY&apos;s channel 8 (~2365 nm) covering four CO
absorption lines.
The focus of this paper is to demonstrate that quantitative information
on  carbon monoxide (CO) on a global scale can be retrieved from SCIAMACHY.
It is shown that plumes of CO resulting from, e.g.
biomass burning in Africa,
are clearly detectable with SCIAMACHY.
The SCIAMACHY CO columns are in good agreement with the CO column
data product of MOPITT (V3). For example, the correlation
between SCIAMACHY and MOPITT CO columns
for cloud free pixels over land
is typically in the
range &lt;i&gt;r&lt;/i&gt;=0.4&amp;ndash;0.7, where &lt;i&gt;r&lt;/i&gt; is the correlation coefficient.
In order to retrieve good CO columns it was
necessary to improve the calibration of the SCIAMACHY nadir spectra.
Nevertheless, there is still room for significant
improvement. The fit residuals, for example,
are dominated by stable and systematic spectral artifacts
on the order of the weak CO lines.
These artifacts are
most pronounced in spectral
regions of strong overlapping methane and water vapour absorption bands.
They
might result from spectrometer slit function uncertainties.
The CO columns of the WFM-DOAS Version 0.4 CO column data product
presented in this paper have been multiplied by
a constant and ground scene independent scaling
factor of 0.5 to quantitatively adjust the WFM-DOAS retrieved CO columns
to the MOPITT CO data. If and how this scaling factor is influenced
by SCIAMACHYs much higher sensitivity to the lower troposphere and
boundary layer CO and/or by the currently not perfect spectral
fitting needs further investigation.</p>
</abstract>
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