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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-3-5803-2003</article-id>
<title-group>
<article-title>Volatile particles formation during PartEmis: a modelling study</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vancassel</surname>
<given-names>X.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sorokin</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Mirabel</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Petzold</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wilson</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Centre de Géochimie de la Surface, Université Louis Pasteur, Strasbourg, France</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Central Institute for Aviation Motors, Moskow, Russia</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Deutsches Zentrum für Luft- und Raumfahrt, Oberpfaffenhofen, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>QinetiQ, Farnborough, UK</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>now at: Atmospheric, Oceanic and Planetary Physics, University of Oxford, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>18</day>
<month>11</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>6</issue>
<fpage>5803</fpage>
<lpage>5829</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/3/5803/2003/acpd-3-5803-2003.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/3/5803/2003/acpd-3-5803-2003.pdf</self-uri>
<abstract>
<p>A modelling study of the formation of volatile particles in a combustor exhaust has been
      carried out in the frame of the PartEmis European project. A kinetic model has been used in
      order to investigate nucleation efficiency of the H&lt;sub&gt;2&lt;/sub&gt;O-H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt; binary mixture in the sampling
      system. A value for the fraction &lt;font face=&quot;Symbol&quot;&gt;e&lt;/font&gt; of the fuel sulphur S(IV) converted into S(VI) has been
      indirectly deduced from comparisons between model results and measurements. In the present
      study, &lt;font face=&quot;Symbol&quot;&gt;e&lt;/font&gt; ranges between roughly 2.5% and 6%, depending on the combustor settings and on
      the microphysical approach used. Soot particles hygroscopicity has also been investigated as
      their activation is a key parameter for contrail formation. Growth factors of monodisperse
      particles exposed to high relative humidity (95%) have been calculated and compared with
      experimental results. The modelling study confirms that the growth factor increases as the
      soot particle size decreases.</p>
</abstract>
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</article-meta>
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