Atmos. Chem. Phys. Discuss., 3, 4183-4358, 2003
www.atmos-chem-phys-discuss.net/3/4183/2003/
doi:10.5194/acpd-3-4183-2003
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This discussion paper has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP.
Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
R. Atkinson
Air Pollution Research Center, and Department of Environmental Sciences, and Department of Chemistry, University of California, Riverside, CA 92507, USA

Abstract. The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented ove the entire temperature range for which measurements have been made (~180–2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented.

Citation: Atkinson, R.: Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes, Atmos. Chem. Phys. Discuss., 3, 4183-4358, doi:10.5194/acpd-3-4183-2003, 2003.
 
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