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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-3-3769-2003</article-id>
<title-group>
<article-title>Overview of the field measurement campaign in Hyytiälä,  August 2001 in the framework of the EU project OSOA</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Boy</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Petäja</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dal Maso</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rannik</surname>
<given-names>Ü.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rinne</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Aalto</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Laaksonen</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vaattovaara</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Joutsensaari</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hoffmann</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Warnke</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Apostolaki</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stephanou</surname>
<given-names>E. G.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tsapakis</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kouvarakis</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pio</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Carvalho</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Römpp</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Moortgat</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Spirig</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Guenther</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Greenberg</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ciccioli</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kulmala</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Dept. of Physical Sciences, University of Helsinki, P.O. Box 64, FIN-00014, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>University of Kuopio, Kuopio, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institut für Specktrochemie, Dortmund, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Environmental Chemical Processes Laboratory &amp;ndash; University of Crete, GR-71409 Heraklion, Greece</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Universidade de Aveiro, Departamento de Ambiente e Ordenamento, Portugal</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>Max-Planck-Institut für Chemie, Atmospheric Chemistry Division, D-55020, Germany</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Atmospheric Chemistry Division, National Centre for Atmospheric Research, Boulder, CO, USA</addr-line>
</aff>
<aff id="aff8">
<label>8</label>
<addr-line>Instituto di Metodologie Chimiche, Area della Ricerca del CNR di Montelibretti, Italy</addr-line>
</aff>
<pub-date pub-type="epub">
<day>25</day>
<month>07</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>4</issue>
<fpage>3769</fpage>
<lpage>3831</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/3/3769/2003/acpd-3-3769-2003.html">This article is available from http://www.atmos-chem-phys-discuss.net/3/3769/2003/acpd-3-3769-2003.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/3/3769/2003/acpd-3-3769-2003.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/3/3769/2003/acpd-3-3769-2003.pdf</self-uri>
<abstract>
<p>As one part of the OSOA (Origin and formation of Secondary Organic Aerosols) project, two
      intensive field campaigns were conducted in Melpitz, Germany and
      Hyytiälä, Finland. This paper gives an overview of the measurements made during the
      Hyytiälä campaign, which was held between the 1st and 16th of August 2001. Various instrumental techniques were used to achieve
      physical and chemical characterisation of aerosols and to investigate possible precursor gases.&lt;br&gt;
      &lt;br&gt;
      During the OSOA campaign in Hyytiälä, particle formation was observed on three consecutive days
      at the beginning of the campaign (1 to 3 August 2001) and on three days later on. The
      investigation of the meteorological situation divided the campaign into two parts. During the first
      three days of August, relatively cold and clean air masses from northwest passed over the station
      (condensation sink &amp;ndash; CS: &amp;lt;0.002 s&lt;sup&gt;&amp;minus;1&lt;/sup&gt;, NO&lt;sub&gt;x&lt;/sub&gt;: &amp;lt;
      0.5 ppb). Daily particle bursts of one fraction of the nucleation mode aerosols (3&amp;ndash;10\,nm) with number concentrations between
      600&amp;ndash;1200 particles cm&lt;sup&gt;-3&lt;/sup&gt; were observed. After this period, warmer and more polluted air from south-west to south-east
      arrived at the station (CS: 0.002-0.01 s&lt;sup&gt;&amp;minus;1&lt;/sup&gt;, NO&lt;sub&gt;x&lt;/sub&gt;:
      0.5&amp;ndash;4 ppb) and during these 13 days only three events were observed. These events were not as apparent as those that occurred during the earlier
      period of the campaign. The chemical analyses from different institutes of
      PM&lt;sub&gt;2&lt;/sub&gt;, PM&lt;sub&gt;2.5&lt;/sub&gt; and PM&lt;sub&gt;10&lt;/sub&gt; particles confirmed the assumption that organic matter from the oxidation of various terpenes
      contributed to the formation of secondary organic aerosols (SOA). Concerning these conclusions
      among others, the ratio between formic (oxidation product of isoprene and monoterpenes by ozone)
      and acetic acid (increased by anthropogenic emissions) (ratio=1 to 1.5) and concentration of
      different carboxylic acids (up to 62 ng m&lt;sup&gt;&amp;minus;3&lt;/sup&gt;) were investigated. Gas/particle partitioning of five
      photo-oxidation products from &amp;alpha;- and
      &amp;beta;-pinene resulted in higher concentrations for pinonic, nor
      pinonic and pinic acids in the particle phase than in the gas phase, which indicates preference to the
      particle phase for these compounds. The average growth factors (GF) from
      100 nm particles in water vapour gave a diurnal pattern with a maximum during daytime and values between 1.2 and
      1.7. On average, the amount of secondary organic carbon reached values around of
      19% of the sampled aerosols and the results indicate that formation of SOA with the influence of
      photo-oxidation products from terpenes was the reason for the observed particle bursts during the
      campaign. However, correlations between the precursor gases or the favourable condensing species
      with the monitored nucleation mode particles were not found. For the investigated time period other
      factors like the condensation sink of newly formed particles to the pre-existing aerosols,
      temperature and solar irradiance seem to be more important steering parameters for the production
      of new aerosols.&lt;br&gt;
      &lt;br&gt;
      Another open question concerns the vertical distribution of the formation of SOA. For this reason
      measurements were conducted at different altitudes using a tethered balloon platform with particle
      sampling and particle counting equipment. They were incorporated with eddy covariance (EC) flux
      measurements made at 23 m above ground level. The results give first indications that the process
      of the production of new aerosols happens throughout the planetary boundary layer (PBL), whereby
      different parameters e.g. temperature, CS, solar irradiance or concentration of monoterpenes are
      responsible for the location of the vertical maximum.</p>
</abstract>
<counts><page-count count="63"/></counts>
</article-meta>
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