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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-3-1051-2003</article-id>
<title-group>
<article-title>Dynamics and chemistry of vortex remnants in late Arctic spring 1997 and 2000: Simulations with the Chemical Lagrangian Model of the Stratosphere (CLaMS)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Konopka</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Grooß</surname>
<given-names>J.-U.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bausch</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Müller</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>McKenna</surname>
<given-names>D. S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Morgenstern</surname>
<given-names>O.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Orsolini</surname>
<given-names>Y.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute for Stratospheric Chemistry (ICG-I), 52425 Jülich, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>National Center for Atmospheric Research, Boulder, CO, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Max Planck Institut für Meteorologie, Hamburg, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Norwegian Institute for Air Research (NILU), Kjeller, Norway</addr-line>
</aff>
<pub-date pub-type="epub">
<day>25</day>
<month>02</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>1</issue>
<fpage>1051</fpage>
<lpage>1080</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/3/1051/2003/acpd-3-1051-2003.html">This article is available from http://www.atmos-chem-phys-discuss.net/3/1051/2003/acpd-3-1051-2003.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/3/1051/2003/acpd-3-1051-2003.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/3/1051/2003/acpd-3-1051-2003.pdf</self-uri>
<abstract>
<p>High resolution simulations of the chemical composition of the
      Arctic stratosphere during late spring 1997 and 2000 have been conducted with the Chemical Lagrangian Model of the Stratosphere
      (CLaMS). The simulations were performed for the entire northern hemisphere on
      two isentropic levels 450 K (~18 km) and 585 K (~24 km).&lt;br&gt;
      &lt;br&gt;
      The spatial distribution and the lifetime of the vortex remnants formed after the vortex breakup in May 1997
      show a completely different behavior above and below 20 km. Above 20 km, vortex remnants effectively propagate southward
      (up to 40&amp;deg; N)  and are &amp;quot;frozen&apos;&apos; in the summer circulation without significant mixing.
      Below 20 km the southward propagation of the remnants is bounded by the subtropical jet near
      55&amp;deg; N. Their lifetime is shorter by a factor of 2 than above 20 km, owing to significant stirring below this altitude.
      The behavior of vortex remnants formed in March 2000 is similar but, due to an earlier vortex breakup, dominated until mid of May
      by westerly winds, even above 20 km.&lt;br&gt;
      &lt;br&gt;
      Vortex remnants formed in May 1997 are characterized by large mixing ratios of HCl indicating a negligible contribution
      of the halogen-induced ozone loss. In contrast, mid-latitude ozone loss in late
      boreal spring 2000 is dominated by an irreversible transport of the ozone-depleted
      polar air masses (dilution) and, until mid of April, by halogen-induced ozone destruction within the vortex remnants.
      By varying the effective diffusivity of CLaMS, the impact of mixing on the formation of
      ClONO&lt;sub&gt;2&lt;/sub&gt; and ozone depletion is considered. In particular, the photochemical decomposition of
      HNO&lt;sub&gt;3&lt;/sub&gt; and not mixing with NO&lt;sub&gt;x&lt;/sub&gt;-rich mid-latitude air is the main source of
      NO&lt;sub&gt;x&lt;/sub&gt; within the vortex remnants in March and April 2000. Ozone depletion in the remnants is driven by
      ClO&lt;sub&gt;x&lt;/sub&gt; photolytically formed from ClONO&lt;sub&gt;2&lt;/sub&gt; and can be properly resolved for
      CLaMS spatial resolution better then 100\,km. At 450 K, ozone loss in the vortex remnants
      contributes by ~2% to the ozone deficit poleward of 30&amp;deg; N.</p>
</abstract>
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