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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-2-875-2002</article-id>
<title-group>
<article-title>Redistribution of trace gases by convective clouds – mixed-phase processes</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yin</surname>
<given-names>Y.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Carslaw</surname>
<given-names>K. S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Parker</surname>
<given-names>D. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute for Atmospheric Science, School of the Environment, University of Leeds, Leeds, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>24</day>
<month>06</month>
<year>2002</year>
</pub-date>
<volume>2</volume>
<issue>3</issue>
<fpage>875</fpage>
<lpage>903</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>The efficiency of gas transport to the free and upper troposphere in
      convective clouds is investigated in an axisymmetric dynamic cloud model with detailed microphysics. In particular, we examine the
      sensitivity of gas transport to the treatment of gas uptake by different ice hydrometeors. Two parameters are used to describe this
      uptake. The gas retention coefficient defines the fraction of dissolved gas that is retained in an ice particle upon freezing, which
      includes also the riming process. We also define a gas burial efficiency defining the amount of gas entrapped in ice crystals
      growing by vapour diffusion. Model calculations are performed for continental and maritime clouds using a complete range of gas
      solubilities, retention coefficients and burial efficiencies. The results show that the magnitude of the gas retention coefficient is
      much more important for gas transport in maritime clouds than in continental clouds.  The cause of this difference lies in the
      different microphysical processes dominating the formation and evolution of hydrometeors in the two cloud types. For highly soluble
      gases, the amount of gas transported to the free troposphere in maritime clouds falls approximately linearly by a factor of 12 as the retention
      coefficient is varied between 0 and 1. Gas transport is relatively insensitive to the magnitude of the gas burial efficiency. However, the burial
      efficiency strongly controls the concentration of trace gases inside anvil ice crystals, which subsequently form cirrus clouds.</p>
</abstract>
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