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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-2-1655-2002</article-id>
<title-group>
<article-title>The Hohenpeissenberg aerosol formation experiment (HAFEX): a long-term study including size-resolved aerosol, H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;, OH, and monoterpenes measurements</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Birmili</surname>
<given-names>W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Berresheim</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Plass-Dülmer</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Elste</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gilge</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wiedensohler</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Uhrner</surname>
<given-names>U.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>University of Birmingham, Division of Environmental Health and Risk Management, Birmingham, B15 2TT, UK</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>German Weather Service, Meteorological Observatory Hohenpeissenberg (MOHp), Albin-Schwaiger-Weg 10, 83282 Hohenpeissenberg, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institute for Tropospheric Research, Permoserstrasse 15, 04303 Leipzig, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>28</day>
<month>10</month>
<year>2002</year>
</pub-date>
<volume>2</volume>
<issue>5</issue>
<fpage>1655</fpage>
<lpage>1697</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/2/1655/2002/acpd-2-1655-2002.html">This article is available from http://www.atmos-chem-phys-discuss.net/2/1655/2002/acpd-2-1655-2002.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys-discuss.net/2/1655/2002/acpd-2-1655-2002.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys-discuss.net/2/1655/2002/acpd-2-1655-2002.pdf</self-uri>
<abstract>
<p>Ambient aerosol size distributions
      (&amp;gt; 3 nm) and OH, H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;, and terpene concentrations
      were measured from April 1998 to August 2000 at a rural continental site in southern Germany.
      New particle formation (NPF) events were detected on 18% of all days, typically during midday hours under sunny and dry conditions.
      Surprisingly, most NPF events occurred during spring and winter, whereas the concentrations of aerosol precursors
      (H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;, monoterpenes) clearly peaked in summer. The number of newly formed particles
      correlated significantly with solar irradiance and ambient levels of H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4
      &lt;/sub&gt;and anti-correlated, especially in the cold season, with relative humidity and the condensational sink provided by pre-existing particles.
      The particle formation rates were experimentally estimated to be on order of
      1 cm&lt;sup&gt;-3&lt;/sup&gt; s&lt;sup&gt;-1&lt;/sup&gt;. Binary homogeneous H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;-H&lt;sub&gt;2&lt;/sub&gt;O nucleation rates calculated from measured
      H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt; were substantially lower than this, even if assuming particle
      formation under the thermodynamic conditions on top of the boundary layer.
      The nucleation mode particle growth rates derived from the evolution of the size distribution
      were 2.6 nm h&lt;sup&gt;-1&lt;/sup&gt; on average, with a fraction of 0.7 nm h&lt;sup&gt;-1&lt;/sup&gt; attributed to
      the co-condensation of H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;/H&lt;sub&gt;2&lt;/sub&gt;O/NH&lt;sub&gt;3&lt;/sub&gt;.
      Turn-over rate calculations of measured monoterpenes and aromatic hydrocarbons suggest that especially the oxidation
      products of monoterpenes may contribute to the observed particle growth, although
      no indications were found that the reaction products of organic compounds would generally control the occurrence of NPF events.</p>
</abstract>
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